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机械化学法对含氯有机物的脱氯研究进展
引用本文:胡汉芳,彭政.机械化学法对含氯有机物的脱氯研究进展[J].工业安全与环保,2011,37(2):24-26.
作者姓名:胡汉芳  彭政
作者单位:1. 中钢集团天澄环保科技股份有限公司,武汉,430205
2. 环境保护部环境保护信息中心,北京,100035
摘    要:评述了机械化学法脱氯的影响因素、反应机制、机械能与脱氯反应转化率的理论分析和脱氯研究中的分析方法.影响机械化学法脱氯效果的重要影响因素为机械能、脱氯剂、脱氯剂与处理物的混合比.脱氯反应中.主要存在脱氯形成自由基以及氢化和聚合反应两种反应路径.机械能与含氯有机物的分解率呈线性关系.

关 键 词:机械化学  含氯有机物  脱氯

Research Progress in Dechlorination of Organo-chlorinated Compounds in Mechanochemical Treatment
HU Hanfang,PENG Zheng.Research Progress in Dechlorination of Organo-chlorinated Compounds in Mechanochemical Treatment[J].Industrial Safety and Dust Control,2011,37(2):24-26.
Authors:HU Hanfang  PENG Zheng
Institution:HU Hanfang1 PENG Zheng2(1.Sinosteel Tiancheng Environmental Protection Science and Technology Co.,Ltd.Wuhan 430205)
Abstract:This paper describes the affecting factors of mechanochemical dechlorination,reaction mechanism,theoretical analysis on mechanical energy dechlorinating rate and dechlorination research analysis methods.The important factors affecting dechlorination effects by mechanochemical treatment include mechanical energy,types of dechlorinating agent and blending ratio of mixture.In dechlorinating process,there mainly exist two pathways,the radicals formed from dechlorinating reaction,and polymerization and hydrolysi...
Keywords:mechanochemical treatment organo-chlorinated compounds dechlorination  
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