Safety and kinetic parameters analysis for 1,1,-Di(tert-butylperoxy) cyclohexane mixed with monoammonium phosphate |
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| Institution: | 1. Department of Safety Health and Environmental Engineering, National Kaohsiung First University of Science and Technology, Kaohsiung 824, Taiwan, ROC;2. Department of Safety Health and Environmental Engineering, Central Taiwan University of Science and Technology, Taichung 40601, Taiwan, ROC;3. Department of Health and Nutrition Biotechnology, Asia University, Taichung 41354, Taiwan, ROC;4. Chemical Engineering, Texas A&M University, USA;1. Department of Civil Engineering, School of Engineering, University of Minho, Campus de Gualtar, 4710-057 Braga, Portugal;2. Municipality of Barcelos, Portugal;1. Institute of Health and Industrial Safety-LRPI, Batna University, 05000 Batna, Algeria;2. Department of Production and Quality Engineering, Norwegian University of Science and Technology, NO 7491 Trondheim, Norway;1. Centre de recherche nucléaire de birine, BP 180, Djelfa 17200, Algeria;2. Facoltà di Ingegneria, Università di Pisa, Via Diotisalvi, 2, Pisa, Italy;3. University of El-Oued, 39000, Algeria;4. Université Ferhat Abbas de Setif, Algeria;1. Deakin University, Institute for Frontier Materials, Waurn Ponds, Victoria 3216, Australia;2. Deakin University, School of Engineering, Faculty of Science and Technology, Geelong Waurn Ponds Campus, Waurn Ponds, Victoria 3216, Australia;3. Department of Materials Science and Engineering, Delft University of Technology, Mekelweg 2, 2628 CD Delft, The Netherlands;4. Department of Metallurgical and Materials Engineering, Ferdowsi University of Mashhad, Mashhad, Iran |
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| Abstract: | Runaway reactions by organic peroxides have occurred throughout the world. In this study, we used 1,1,-Di(tert-butylperoxy) cyclohexane (CH) 70 mass% as the main material, which was extensively employed as initiator for styrene in polymerization. Fire extinguishers are the first fire-fighting apparatus when fires occur. If a fire extinguisher has sat idle for a long time, which would cause the extinguishing agent to damp, it cannot achieve the desired effect and be properly handled at the start of the accident, thereby causing more casualties and property losses. CH 70 mass% was employed to mixed with monoammonium phosphate (MAP) for understanding the phenomenon by applying differential scanning calorimetry (DSC). Safety parameters also were carried out for more deeply understanding the basic characteristics for preventing an accident from occurring, in terms of applying CH 70 mass% as the initiator in the manufacturing process. |
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| Keywords: | Runaway reactions 1 1 -Di(tert-butylperoxy) cyclohexane (CH) Monoammonium phosphate (MAP) Differential scanning calorimetry (DSC) Safety parameters |
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