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电动力学作用下多溴联苯醚在土壤中的迁移特性
引用本文:解清杰,姚一凡,吴春笃,范翠萍,叶丹,时杰华.电动力学作用下多溴联苯醚在土壤中的迁移特性[J].化工环保,2013,33(3):189-192.
作者姓名:解清杰  姚一凡  吴春笃  范翠萍  叶丹  时杰华
作者单位:1.江苏大学环境学院,江苏镇江212013; 2.扬州环境资源职业技术学院,江苏,扬州225002
基金项目:江苏省科技支撑计划资助项目,国家博士后基金资助项目
摘    要:以4,4′-二溴联苯醚(BDE-15)为研究对象,探讨了电极电压、初始土壤pH、β-环糊精加入量、NaCl加入量等工艺条件对多溴联苯醚在土壤中迁移效果的影响。实验结果表明:在电极电压为5~15V范围内,随着电极电压的升高,土壤中BDE-15的迁移效果增强;初始土壤为酸性时、加入β-环糊精或NaCl后,土壤中BDE-15的迁移效果均增强。本实验选择的最佳工作条件为:电极电压15V,初始土壤pH3,β-环糊精的加入量3g,NaCl加入量5g。

关 键 词:多溴联苯醚  4  4′-二溴联苯醚  土壤修复  电迁移  电渗析  
收稿时间:2013-06-25

Migration Characteristics of PBDEs in Soil by Electrokinetics
Xie Qingjie , Yao Yifan , Wu Chundu , Fan Cuiping , Ye Dan , Shi Jiehua.Migration Characteristics of PBDEs in Soil by Electrokinetics[J].Environmental Protection of Chemical Industry,2013,33(3):189-192.
Authors:Xie Qingjie  Yao Yifan  Wu Chundu  Fan Cuiping  Ye Dan  Shi Jiehua
Institution:1. College of Environment,Jiangsu University,Zhenjiang Jiangsu 212013,China; 2. Yangzhou Vocational College of Environment and Resources,Yangzhou Jiangsu 225002,China
Abstract:Taking 4,4′-dibromodiphenyl ether (BDE-15) as the research object,the factors affecting the migration of polybrominated diphenyl ethers (PBDEs) in soil were studied,such as:electrode voltage,initial soil pH,β-cyclodextrin dosage and NaCl dosage. The experimental results show that:In the electrode voltage of 5–15 V,the migration effect of BDE-15 in soil is improved with the rising of electrode voltage;when the initial soil is acidic,or β-cyclodextrin or NaCl is added,the migration effect is also improved. The optimum process conditions are as follows:electrode voltage 15 V,initial soil pH 3,β-cyclodextrin dosage 3 g,NaCl dosage 5 g.
Keywords:polybrominated diphenyl ethers (PBDEs)  4  4'-dibromodiphenyl ether (BDE-15)  soil remediation  electromigration  electrodialysis
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