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酸化处理的活性碳纤维负载氧化镧催化还原NO
引用本文:王群敬,李彩亭,路培,李群,罗瑶,田立辉.酸化处理的活性碳纤维负载氧化镧催化还原NO[J].化工环保,2008,28(4).
作者姓名:王群敬  李彩亭  路培  李群  罗瑶  田立辉
作者单位:湖南大学,环境科学与工程学院,湖南,长沙,410082
摘    要:采用浸渍法制备了负载La2O3的经HNO3活化的活性碳纤维(La2O3/HNO3/ACF)。研究了La2O3/HNO3/ACF对NO的催化活性,研究结果表明:La2O3/HNO3/ACF的低温催化活性远低于La2O3/ACF和HNO3/ACF;随反应温度升高,La2O3/HNO3/ACF对NO的去除率显著提高。La2O3/HNO3/ACF的高温(350℃以上)催化活性很高,优于La2O3/ACF等其他催化剂,且催化活性稳定性很好。La2O3负载量影响La2O3/HNO3/ACF的催化活性,18%La2O3/HNO3/ACF的高温催化活性和活性稳定性最佳,催化活性维持在10h以上。催化剂的扫描电子显微镜和x射线衍射分析结果表明,负载的La2O3多以非晶状态存在于催化剂的表面和内部的孔隙中。

关 键 词:活性碳纤维  负载  氧化镧  一氧化氮  催化还原

Catalytic Reduction of NO by La2O3 Supported on Acidified Activated Carbon Fibers
Wang Qunjing,Li Caiting,Lu Pei,Li aun,Luo Yao,Tian Lihui.Catalytic Reduction of NO by La2O3 Supported on Acidified Activated Carbon Fibers[J].Environmental Protection of Chemical Industry,2008,28(4).
Authors:Wang Qunjing  Li Caiting  Lu Pei  Li aun  Luo Yao  Tian Lihui
Abstract:The catalyst of La_2O_3 supported on Activated Carbon Fibers acidified by HNO_3 (La_2O_3/ HNO_3/ACF) was prepared by immersion method.The catalytic activity of La_2O_3/HNO_3/ACF to NO was studied.The results show that:The catalytic activity of La_2O_3/HNO_3/ACF is far less than that of La_2O_3/ACF and HNO_3/ACF at low temperature;With the temperature increase,the removal rate of NO by La_2O_3/HNO_3/ACF is obviously improved;The catalytic activity of La_2O_3/HNO_3/ACF is superior to that of La_2O_3/ACF and o...
Keywords:activated carbon fiber  load  lanthanum oxide  nitrogen oxide  catalytic reduction  
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