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Preformed Amide-containing biopolymer for Improving the Environmental Performance of Synthesized Urea–formaldehyde in Agro-fiber Composites
Authors:Altaf H Basta  Houssni El-Saied  Jerrold E Winandy  Ronald Sabo
Institution:(1) Cellulose & Paper Dept, National Research Centre, Dokki, Cairo, 12622, Egypt;(2) University of Minnesota, St. Paul, MN 55108, USA;(3) US Forest Products Laboratory, Madison, WI, USA
Abstract:Investigations have continued for production high performance agro-based composites using environmentally acceptable approaches. This study examines the role of adding amide-containing biopolymers during synthesis of urea–formaldehyde (UF) on properties of adhesive produced, especially its adhesion potential. The environmental performance of UF-resin synthesized in the presence of modified amide-containing biopolymer was evaluated by evaluating the free-HCHO of both adhesive (during processing) and of the eventual engineered composite product. Also, the benefits of this synthesis-modified adhesive in enhancing the bondability of sugar-cane fibers used in engineered composite panels was evaluated and compared to using UF-resin. The results obtained show that, static bending of the produced composites varied from 27.7 to 33.13 N/mm2 of modulus of rupture (MOR) and from 2860 to 3374 N/mm2 of Modulus of Elasticity (MOE); while for internal bond (IB) it’s varied from 0.64 to 0.866 N/mm2. Based on the ANSI and EN Standards modified UF-based agro composites produced meet the performance requirements for high grade particleboards with respect to static bending strength. These agro-based composite also tested out as having free-HCHO values of ~13 mg/100 g board.
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