Preformed Amide-containing biopolymer for Improving the Environmental Performance of Synthesized Urea–formaldehyde in Agro-fiber Composites |
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Authors: | Altaf H Basta Houssni El-Saied Jerrold E Winandy Ronald Sabo |
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Institution: | (1) Cellulose & Paper Dept, National Research Centre, Dokki, Cairo, 12622, Egypt;(2) University of Minnesota, St. Paul, MN 55108, USA;(3) US Forest Products Laboratory, Madison, WI, USA |
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Abstract: | Investigations have continued for production high performance agro-based composites using environmentally acceptable approaches.
This study examines the role of adding amide-containing biopolymers during synthesis of urea–formaldehyde (UF) on properties
of adhesive produced, especially its adhesion potential. The environmental performance of UF-resin synthesized in the presence
of modified amide-containing biopolymer was evaluated by evaluating the free-HCHO of both adhesive (during processing) and
of the eventual engineered composite product. Also, the benefits of this synthesis-modified adhesive in enhancing the bondability
of sugar-cane fibers used in engineered composite panels was evaluated and compared to using UF-resin. The results obtained
show that, static bending of the produced composites varied from 27.7 to 33.13 N/mm2 of modulus of rupture (MOR) and from 2860 to 3374 N/mm2 of Modulus of Elasticity (MOE); while for internal bond (IB) it’s varied from 0.64 to 0.866 N/mm2. Based on the ANSI and EN Standards modified UF-based agro composites produced meet the performance requirements for high
grade particleboards with respect to static bending strength. These agro-based composite also tested out as having free-HCHO
values of ~13 mg/100 g board. |
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