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NaClO_2/氨水溶液同时脱除SO_2和NO的热力学研究
引用本文:张晓波,郭瑞堂,潘卫国,徐宏建,吴黎明,彭皓.NaClO_2/氨水溶液同时脱除SO_2和NO的热力学研究[J].电力环境保护,2010,26(4):15-17.
作者姓名:张晓波  郭瑞堂  潘卫国  徐宏建  吴黎明  彭皓
作者单位:1. 上海电力学院能源与环境工程学院,上海,200090
2. 上海瑞帆环境工程有限公司,上海,200080
基金项目:上海市教委科研创新项目,上海高校选拔培养优秀青年教师专项基金 
摘    要:利用化学热力学基本原理分别对NaClO2/氨水溶液同时脱除SO2、NO的反应过程中摩尔反应吉布斯自由能变、摩尔反应焓变、化学反应平衡常数以及化学反应达到平衡时的SO2和NO的分压力进行了计算,结果表明:利用NaClO2/氨水溶液同时脱除SO2、NO是可行的,且SO2和NO的脱除效率几乎可以达到100%。

关 键 词:NaClO2/氨水溶液  同时脱除SO2、NO  化学热力学

Thermodynamic study of NaClO2/ammonia solution simultaneous removal of SO2 and NO
ZHANG Xiao-bo,GUO Rui-tang,PAN Wei-guo,et al.Thermodynamic study of NaClO2/ammonia solution simultaneous removal of SO2 and NO[J].Electric Power Environmental Protection,2010,26(4):15-17.
Authors:ZHANG Xiao-bo  GUO Rui-tang  PAN Wei-guo  
Institution:ZHANG Xiao-bo,GUO Rui-tang,PAN Wei-guo,et al
Abstract:Molar reaction Gibbs function change,molar reaction enthalpy change,equilibrium constant and the equilibrium partial pressure of SO2 and NO for the reaction of simultaneous removal of SO2 and NO by using aqueous NaClO2/ammonia solution were calculated based on the principle of chemical thermodynamics.As can be seen from the results,simultaneous removal of SO2 and NO by using NaClO2/ ammonia solution is available,and the removal efficiencies are nearly 100%.
Keywords:NaClO2/ammonia solution  simultaneous removal of SO2  NO  chemical thermodynamics  
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