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Effects of composing on sorption capacity of bagasse-based chars
Authors:Lo Tsui  Ming-An Juang
Institution:1. Department of Chemistry, Erode Arts College, Erode 638 008, TN, India;2. Department of Chemistry, AA Govt Arts College, Namakkal 637 002, TN, India;3. Department of Chemistry, Sri Vasavi College, Erode 638 316, TN, India;1. Department of Environmental Health, Zabol University of Medical Sciences, Zabol, Iran;2. Department of Physics, Faculty of Science, University of Zabol, Zabol, Iran;3. Young Researchers and Elite Club, Science and Research Branch, Islamic Azad University Hamedan, Iran;4. Department of Chemistry, University of Gujrat, Gujrat, 50700, Pakistan;5. PhD of Environmental Health, Infectious Diseases and Tropical Medicine Research Center, Resistant Tuberculosis Institute, Zahedan University of Medical Sciences, Iran;6. Chemyistry Department, Universidade Federal de São Paulo, São Paulo, Brazil;1. Department of Chemistry, University of Dumlupinar, Kutahya, Turkey;2. Department of Chemical Engineering, Curtin University, GPO Box U1987, Perth, WA 6845, Australia;1. Institute for Water Quality, Resource, and Waste Management, Technische Universität Wien, Karlsplatz 13/226.2, 1040 Wien, Austria;2. School of Agricultural Sciences, College of Agricultural and Environmental Sciences, Makerere University, P.O. Box 7062, Kampala, Uganda
Abstract:A fresh bagasse sample (0-month) and two composted bagasse and pig manure mixed samples (1-month and 6-month) were used to produce carbon chars. Sample pyrolysis showed greater carbon char yields were obtained from the compost samples than from the bagasse sample. Fourier transform infrared spectra suggested that the chemical structures of the bagasse sample and the two compost samples were quite different, but that the three carbon chars obtained from those precursors were similar. Among the three pyrolyzed chars, the 0-month bagasse char displayed the largest sorption capacity of 3333 mg kg?1 for the hydrophilic pollutant phenol, presumably resulting from its greater carbon content and O/C ratio. However, the sorption capacities for the hydrophobic pollutant naphthalene of the tow compost chars (3-month, 2001 mg kg?1; 6-month, 1667 mg kg?1) were greater than that of the 0-month bagasse char (1428 mg kg?1). The results indicate that the compost chars had a greater preferential affinity for naphthalene than that in the bagasse char, suggesting that the compost chars possessed greater hydrophobicity.
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