水相和泥浆系统中地下水成分对高锰酸钾氧化TCE的影响 |
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引用本文: | 逯志昌,邱兆富,吕树光,何龙,隋倩,林匡飞,刘勇弟.水相和泥浆系统中地下水成分对高锰酸钾氧化TCE的影响[J].环境工程学报,2012,6(12):4529-4534. |
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作者姓名: | 逯志昌 邱兆富 吕树光 何龙 隋倩 林匡飞 刘勇弟 |
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作者单位: | 华东理工大学资源与环境工程学院,国家环境保护化工过程环境风险评价与控制重点实验室,上海200237 |
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基金项目: | 环保公益性行业科研专项(201109013);上海市自然科学基金面上项目(12ZR1408000) |
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摘 要: | 三氯乙烯(TCE)是污染土壤和地下水中检出率较高的氯代有机物。以TCE为研究对象,考察了地下水无机成分和腐殖酸对高锰酸钾氧化TCE的影响,研究了不同离子强度下的MnO,颗粒行为,并测定了泥浆系统中TCE的氧化效果,结果表明:当TCE初始浓度为20mg/L、高锰酸钾与TCE的摩尔比为2:1,离子浓度〈0.1mol/L时,TCE去除率可达98%以上,Na^+、Cl^-、HCO3-对TCE的去除率影响甚微,但离子强度对MnO2的沉淀生成影响显著;0.1mol/L的K^+对TCE的去除有一定程度的抑制;0.1mmol/L的Fe^2+和腐殖酸对TCE的氧化有显著负面影响。泥浆系统实验进一步验证了有机质对高锰酸钾氧化TCE的影响很大。
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关 键 词: | 高锰酸钾 三氯乙烯 污染地下水 泥浆系统 |
Effects of groundwater constituents on trichloroethylene oxidation using permanganate in aqueous and slurry systems |
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Institution: | State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process,School of Resources and Environmental Engineering,East China University of Science and Technology,Shanghai 200237,China;State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process,School of Resources and Environmental Engineering,East China University of Science and Technology,Shanghai 200237,China;State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process,School of Resources and Environmental Engineering,East China University of Science and Technology,Shanghai 200237,China;State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process,School of Resources and Environmental Engineering,East China University of Science and Technology,Shanghai 200237,China;State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process,School of Resources and Environmental Engineering,East China University of Science and Technology,Shanghai 200237,China;State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process,School of Resources and Environmental Engineering,East China University of Science and Technology,Shanghai 200237,China;State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process,School of Resources and Environmental Engineering,East China University of Science and Technology,Shanghai 200237,China |
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Abstract: | |
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Keywords: | potassium permanganate trichloroethylene contaminated groundwater slurry system |
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