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不同高级氧化法对水中低浓度药物甲硝唑降解过程的比较
引用本文:熊振湖,陈在旭,刘建明.不同高级氧化法对水中低浓度药物甲硝唑降解过程的比较[J].环境工程学报,2009,3(3):465-469.
作者姓名:熊振湖  陈在旭  刘建明
作者单位:天津城市建设学院环境与市政工程系,天津,300384
基金项目:天津市自然科学基金重点项目(07JCZDJC01700)
摘    要:采用UV、H2O2、UV/H2O2、Fenton、UV/Fenton和UV/TiO2方法,对水中低浓度的药物甲硝唑进行降解。通过HPLC和UV-Vis光谱得到的甲硝唑去除率。详细讨论了Fe2+、TiO2和H2O2的初始浓度以及溶液的初始pH值对降解效率的影响。结果表明,UV/Fenton和UV/TiO2 2种系统对水中低浓度甲硝唑均有很好的去除效果,但前者的光催化效率更高。在甲硝唑浓度=6 μmol/L,H2O2和Fe2+的初始浓度分别为0.5 mg/L和2.94 μmol/L,pH=4的条件下,UV/Fenton方法对甲硝唑水溶液光催化的最佳效率为95.8%。

关 键 词:甲硝唑  光催化降解  二级出水模拟水溶液
收稿时间:7/6/2008 12:00:00 AM

Comparison of metronidazole degradation by different advanced oxidation processes in low concentration aqueous solutions
Xiong Zhenhu,Chen Zaixu and Liu Jianming.Comparison of metronidazole degradation by different advanced oxidation processes in low concentration aqueous solutions[J].Techniques and Equipment for Environmental Pollution Control,2009,3(3):465-469.
Authors:Xiong Zhenhu  Chen Zaixu and Liu Jianming
Institution:Department of Environmental and Municipal Engineering, Tianjin Institute of Urban Construction, Tianjin 300384,Department of Environmental and Municipal Engineering, Tianjin Institute of Urban Construction, Tianjin 300384 and Department of Environmental and Municipal Engineering, Tianjin Institute of Urban Construction, Tianjin 300384
Abstract:The photocatalytic degradation of the metronidazole was carried out by means of the UV,H2O2,UV/H2O2,Fenton,UV/Fenton,UV/TiO2 advanced oxidation processes.The drug degradation was monitored during the experiment with HPLC and UV-Vis Absorption.The effects of the initial concentrations,for instance Fe2+,TiO2,H2O2,as well as the solution pH on the removal of the drug were discussed.The result suggests that UV/Fenton and UV/TiO2 systems can remove the drug more efficiently from the waters containing metronidazo...
Keywords:UV/Fenton  UV/TiO2
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