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Keggin型Fe-Mo-Zr杂多酸盐光催化剂的制备及性能研究
引用本文:张治宏,王彩花,王晓昌.Keggin型Fe-Mo-Zr杂多酸盐光催化剂的制备及性能研究[J].环境工程学报,2009,3(7):1241-1244.
作者姓名:张治宏  王彩花  王晓昌
作者单位:1. 西安建筑科技大学环境与市政工程学院,西安,710055;西安工业大学材料与化工学院,西安,710032
2. 西安建筑科技大学环境与市政工程学院,西安,710055;西安科技大学能源学院,西安,710054
3. 西安建筑科技大学环境与市政工程学院,西安,710055
摘    要:利用水热合成法制备了Keggin结构的Fe-Mo-Zr杂多酸盐光催化剂,并利用红外光谱(IR)对催化剂进行了表征。实验以酸性大红(GR)为模拟污染物,考察了在紫外灯照射下,Fe-Mo-Zr杂多酸盐的投加量、污染物的浓度和pH值以及外加H2O2对光催化降解效果的影响。实验结果表明,当催化剂的投加量为0.6 g/L,pH为5~7,初始浓度为10 mg/L的GR染料溶液,光照160 min,脱色率可达87.98%。外加H2O2可以提高光催化反应效率。

关 键 词:Keggin结构  Fe-Mo-Zr  杂多酸盐  光催化  大红染料  废水处理

Preparation of Fe-Mo-Zr heteropoly salt with Keggin structureand study on its properties
Zhang Zhihong,Wang Caihua and Wang Xiaochang.Preparation of Fe-Mo-Zr heteropoly salt with Keggin structureand study on its properties[J].Techniques and Equipment for Environmental Pollution Control,2009,3(7):1241-1244.
Authors:Zhang Zhihong  Wang Caihua and Wang Xiaochang
Institution:1.College of Environmental and Municipal Engineering;Xi'an University of Architecture and Technology;Xi'an 710055;China;2.School of Materials and Chemical Engineering;Xi'an Technological University;Xi'an 710032;3.School of Energy Engineering;Xi'an University of Science and Technology;Xi'an 710054;China
Abstract:The photocatalyst of the heteropoly salt containing Fe-Mo-Zr was prepared with the hydrothermal synthesizes reactions and characterized by fourier transform infrared spectroscopy(FT-IR).The influences of the amount of the photocatalyst,initial concentration of acidic great red(GR),pH value of solution and H2O2 added were studied by degradation rate of GR under UV light irradiation.The results of the experiments show that the concentration of GR dye solution is 10 mg/L,and catalyst amount of Fe-Mo-Zr is 0.6 ...
Keywords:Fe-Mo-Zr
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