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催化氧化法处理难生化炼油污水研究
引用本文:侯钰,高峰,桑军强,李本高.催化氧化法处理难生化炼油污水研究[J].环境工程学报,2011,5(1):127-131.
作者姓名:侯钰  高峰  桑军强  李本高
作者单位:石油化工科学研究院,北京,100083
摘    要:以三级生化处理后的炼油污水为研究对象,考察了催化氧化过程的氧化作用和混凝作用,结果表明,催化氧化法去除有机物主要通过将大分子有机物氧化分解为小分子有机物,从而提高污水的可生化性;催化氧化对有机物氧化具有选择性,对苯甲酸和苯胺等芳香类化合物去除效果好,去除率分别达到92.2%和84.8%;对草酸和乙酸等小分子有机酸去除效...

关 键 词:污水处理  催化氧化  机理

Treatment of refining wastewater by catalytic oxidation
Hou Yu,Gao Feng,Sang Junqiang and Li Bengao.Treatment of refining wastewater by catalytic oxidation[J].Techniques and Equipment for Environmental Pollution Control,2011,5(1):127-131.
Authors:Hou Yu  Gao Feng  Sang Junqiang and Li Bengao
Institution:Research Institute of Petroleum Processing, Beijing 100083,China,Research Institute of Petroleum Processing, Beijing 100083,China,Research Institute of Petroleum Processing, Beijing 100083,China and Research Institute of Petroleum Processing, Beijing 100083,China
Abstract:The tertiary biochemical treated refining wastewater was further treated by catalytic oxidation. The results show that the organic macromolecules in the refining wastewater are degraded into smaller ones by catalytic oxidation, resulting in the improvement of the biodegradability. It selectively oxidizes benzyl acid and aniline effectively with the removal rate of 92.2% and 84.8%, respectively; however, it is less effective to the acetic acid and oxalic acid with the removal rate of 13.5% and 10.6%, respectively.
Keywords:wastewater treatment  catalytic oxidation  mechanism
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