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多孔铁-碳-稀土合金填料对高盐废水中氯离子的去除
引用本文:周贵忠,王绚,刘建庭,王兆丰,李少香.多孔铁-碳-稀土合金填料对高盐废水中氯离子的去除[J].环境工程学报,2013,7(6):2167-2172.
作者姓名:周贵忠  王绚  刘建庭  王兆丰  李少香
作者单位:青岛科技大学环境与安全工程学院,青岛,266042
基金项目:国家科技部支撑计划项目(2011BAC10B04)
摘    要:高盐废水是目前水处理领域的难点,主要研究了不同因素下多孔铁碳合金填料对氯离子的去除效果,及Cl-的去除机理。在进水pH为2,停留时间为60 min,Cl-浓度20 000 mg/L条件下进行实验,通过静态实验和连续实验确定Cl-主要去除途径为微电解过程引起的填料吸附。这种合金填料对实际高氯废水也有较好的处理效果,针对变性淀粉废水,在最优条件下填料对废水中氯离子有较强的吸附去除能力,同时COD去除率能达到57%,废水的可生化性得以大幅度提高。

关 键 词:铁-碳-稀土合金填料  高氯废水  变性淀粉废水  可生化性
修稿时间:5/6/2012 12:00:00 AM

Removal of chloride ion in high salt wastewater by porous iron-carbon-rare earth alloy filler
Zhou Guizhong,Wang Xuan,Liu Jianting,Wang Zhaofeng and Li Shaoxiang.Removal of chloride ion in high salt wastewater by porous iron-carbon-rare earth alloy filler[J].Techniques and Equipment for Environmental Pollution Control,2013,7(6):2167-2172.
Authors:Zhou Guizhong  Wang Xuan  Liu Jianting  Wang Zhaofeng and Li Shaoxiang
Institution:College of Environment and Safety Engineering, Qingdao University of Science and Technology, Qingdao 266042, China;College of Environment and Safety Engineering, Qingdao University of Science and Technology, Qingdao 266042, China;College of Environment and Safety Engineering, Qingdao University of Science and Technology, Qingdao 266042, China;College of Environment and Safety Engineering, Qingdao University of Science and Technology, Qingdao 266042, China;College of Environment and Safety Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
Abstract:High salt wastewater, especially the high chlorine wastewater, is difficult to be treated. Chloride removal efficiency of porous iron carbon alloy filler in different factors and an in-depth research of Cl- removal mechanism were studied. The experiments were carried out under the conditions of initial pH of 2, reaction time of 60 min, Cl- concentration of 20 000 mg/L. It had found that the mainly removal pathway of Cl- was filler adsorption caused by micro electrolysis process through static and continuous experiments. Experiments showed that this alloy filler also had a good treatment effect on actual high chlorine wastewater. The filler had strong adsorption capacity on Cl- in modified starch wastewater under the optimal conditions. The removal rate of COD could reach 57% and the biodegradability of wastewater was greatly improved at the same time.
Keywords:iron-carbon-rare earth alloy filler  high chlorine wastewater  modified starch wastewater  biodegradability
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