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负载TiO2/Fe3+的玻璃纤维反应器光催化苯酚
引用本文:王西峰,彭党聪,班云霄.负载TiO2/Fe3+的玻璃纤维反应器光催化苯酚[J].环境工程学报,2012,6(7):2309-2314.
作者姓名:王西峰  彭党聪  班云霄
作者单位:1. 西安建筑科技大学环境与市政工程学院,西安710055 湖南科技大学土木工程学院,湘潭411201
2. 西安建筑科技大学环境与市政工程学院,西安,710055
基金项目:陕西省西部建筑科技重点实验室开放研究基金资助项目(09KF12); 住房和城乡建设部科学技术研究开发项目(2010-K7-13)
摘    要:以玻璃纤维为载体,将TiO2负载到其表面形成了空间玻璃纤维反应器,引入Fe3+作为掺杂改性离子,形成了负载TiO2/Fe3+的空间玻璃纤维光催化反应器,并以高压汞灯为光源进行了光催化降解水中苯酚的实验研究,考察了影响苯酚光催化降解的因素,确定了在UV365~250 W光源照射下,pH为3~5,O2通入量1.0 L/(min.L),反应器内上升流速为0.7 m/min等实验条件下,初始浓度为30 mg/L的苯酚废水经120 min光催化反应后,降解率可达到85%,矿化率可达80%。

关 键 词:二氧化钛  铁掺杂  光催化氧化  苯酚

Photo-catalytic degradation of phenol with TiO2/Fe3+ coated on glass fiber
Wang Xifeng,Peng Dangcong and Ban Yunxiao.Photo-catalytic degradation of phenol with TiO2/Fe3+ coated on glass fiber[J].Techniques and Equipment for Environmental Pollution Control,2012,6(7):2309-2314.
Authors:Wang Xifeng  Peng Dangcong and Ban Yunxiao
Institution:1(1.School of Environmental and Municipal Engineering,Xi’an University of Architecture & Technology,Xi’an 710055,China; 2.School of Civil Engineering,Hunan University of Science and Technology,Xiangtan 411201,China)
Abstract:TiO2/Fe3+/glass fiber was prepared with TiO2 and Fe3+ coated on glass fiber,and Fe3+ was doped as a modification ion.The photocatalytic activity of TiO2/Fe3+/glass fiber was evaluated using phenol as a model substrate.The experimental results demonstrated that TiO2/Fe3+ coated on glass fiber had good degradeation capacity.The optimum conditions evaluated by degradation and mineralization rates of phenol were as follows: wastewater pH of 3~5,O2 of 1.0 L/(min·L),rising velocity of 0.7 m/min,and power of 365 UV high-presser mercury lamp was 250 W.Under the optimum conditions,phenol degradation and mineralization rates could reach 85% and 80%,respectively when initial phenol concentration was 30 mg/L and reaction time lasted 120 min.
Keywords:TiO2  iron doped  photo catalysis  phenol
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