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纳米ZnO/PS薄膜的制备及光降解性能
引用本文:傅敏,冉德超,汤敏,郝丽萌,皮俊敏.纳米ZnO/PS薄膜的制备及光降解性能[J].环境工程学报,2013,7(1):242-246.
作者姓名:傅敏  冉德超  汤敏  郝丽萌  皮俊敏
作者单位:1. 重庆工商大学环境与生物工程学院,重庆,400067
2. 山东省济南市生活废弃物处理中心,济南,250031
3. 綦江县环保局环境监测站,重庆,401420
基金项目:重庆市科委项目(CSTC. 2008BA4012);重庆教委项目(KJZH11214,KJ090727);重庆高校创新团队项目( KJTD201020);重庆工商大学创新型科研项目基金(yjscxx2009-06)
摘    要:利用纳米ZnO与聚苯乙烯(PS)高速共混法制备了一种在紫外光下具有自降解性能的复合薄膜.分析表明,经过KH570处理的纳米ZnO与PS通过化学键的方式桥联在一起.TG分析表明,复合薄膜的耐热性较PS有所提高;SEM图像显示0.5 wt% ZnO在PS薄膜表面分布均匀,经过UV照射后薄膜表面出现光腐蚀现象.复合薄膜紫外光自降解实验表明:0.5 wt% ZnO/PS薄膜在15W的紫外灯照射下,15d的自降解率为3.715%.

关 键 词:纳米ZnO/PS  复合薄膜  自降解
修稿时间:5/6/2010 12:00:00 AM

Preparation and photo degradation of nano-ZnO/polystyrene composite film
Fu Min,Ran Dechao,Tang Min,Hao Limeng and Pi Junmin.Preparation and photo degradation of nano-ZnO/polystyrene composite film[J].Techniques and Equipment for Environmental Pollution Control,2013,7(1):242-246.
Authors:Fu Min  Ran Dechao  Tang Min  Hao Limeng and Pi Junmin
Institution:Environmental and Biological Engineering Institute, Chongqing Technology and Busiess University, Chongqing 400067, China;Domestic Waste Treatment Center, City Administration, Jinan 250031, China;Environmental Monitoring Station, Environmental Protection Bureau of Qijiang County, Chongqing 401420, China;Environmental and Biological Engineering Institute, Chongqing Technology and Busiess University, Chongqing 400067, China;Environmental and Biological Engineering Institute, Chongqing Technology and Busiess University, Chongqing 400067, China
Abstract:Composite film which has self-degradation performance under UV light was prepared by blending nano-ZnO and polystyrene at high speed in this study. Analysis indicates that after adding the coupling agent KH570, nano-ZnO and PS were linked together through chemical bonding. The TG spectra showed that ZnO/PS composite film has higher heat resistant than pure PS. Also, SEM images indicated that 0.5 wt% nano-ZnO were evenly distributed in the PS membrane, however, light corrosion appeared on the membrane surface after UV irradiation. The UV irradiation experiments showed that for a 0.5 wt% ZnO/PS composite film, after 15 days at a UV irradiation power of 15 W, the degradation rate reached 3.715%.
Keywords:nano-ZnO/polystyrene  composite film  self-degradation
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