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Evaluation of non-enteric sources of non-methane volatile organic compound (NMVOC) emissions from dairies
Authors:Myeong Y Chung  Matt Beene  Shawn Ashkan  Charles Krauter  Alam S Hasson
Institution:1. Department of Chemistry, 2555 East San Ramon Avenue M/S SB70, California State University Fresno, Fresno, CA 93740, USA;2. Center for Irrigation Technology, 4370 North Chestnut Avenue, California State University Fresno, Fresno, CA 93740, USA;3. Department of Plant Sciences, 2415 East San Ramon Avenue M/S AS72 California State University Fresno, Fresno, CA 93740, USA;2. USDA-ARS Conservation and Production Research Laboratory, P.O. Drawer 10, Bushland, TX 79012, USA;1. Institute of Environmental Engineering, National Chiao Tung University, Hsinchu 300, Taiwan;2. Environmental Analysis Laboratory, Environmental Protection Administration, Jongli 320, Taiwan;1. Department of Earth and Atmospheric Sciences, 1-22 Earth Sciences Bldg, University of Alberta, Edmonton, AB, Canada T6G 2E3;2. Agriculture and Agri-Food Canada, 5403—1 Avenue South, Lethbridge, AB, Canada T1J 4B1;3. Melbourne School of Land and Environment, The University of Melbourne, Melbourne 3010, VIC, Australia;4. Agriculture and Agri-Food Canada, 960 Carling Ave., Ottawa, ON, Canada K1A 0C6;1. Università degli Studi di Milano, Department of Agricultural and Environmental Sciences, Via Celoria 2, 20133 Milan, Italy;2. Aarhus University, Department of Engineering, Hangøvej 2, 8200 Aarhus N, Denmark;3. University of Southern Denmark, Department of Chemical Engineering, Biotechnology and Environmental Technology, Niels Bohrs Allé 1, 5230 Odense M, Denmark;1. Wageningen UR Livestock Research, P.O. Box 338, 6700 AH Wageningen, The Netherlands;2. Farm Technology Group, Wageningen University, P.O. Box 16, 6700 AA Wageningen, The Netherlands;1. Agriculture and Agri-Food Canada, Science and Technology Branch, 960 Carling Avenue, Ottawa, ON, Canada K1A 0C6;2. Department of Earth and Atmospheric Sciences, University of Alberta, Edmonton, AB, Canada T6G 2H4;3. Ontario Ministry of Agriculture and Food, Guelph, ON, Canada N1G 2W1
Abstract:Dairies are believed to be a major source of volatile organic compounds (VOC) in Central California, but few studies have characterized VOC emissions from these facilities. In this work, samples were collected from six sources of VOCs (Silage, Total Mixed Rations, Lagoons, Flushing Lanes, Open Lots and Bedding) at six dairies in Central California during 2006–2007 using emission isolation flux chambers and polished stainless steel canisters. Samples were analyzed by gas chromatography/mass spectrometry and gas chromatography/flame ionization detection. Forty-eight VOCs were identified and quantified in the samples, including alcohols, carbonyls, alkanes and aromatics. Silage and Total Mixed Rations are the dominant sources of VOCs tested, with ethanol as the major VOC present. Emissions from the remaining sources are two to three orders of magnitude smaller, with carbonyls and aromatics as the main components. The data suggest that animal feed rather than animal waste are the main source of non-enteric VOC emissions from dairies.
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