| 氧化亚铁硫杆菌对电子垃圾焚烧迹地重金属形态的影响 |
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| 引用本文： | 赵国华,高顺芝,罗兴章.氧化亚铁硫杆菌对电子垃圾焚烧迹地重金属形态的影响[J].环境污染治理技术与设备,2014(1):347-352. |
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| 作者姓名： | 赵国华 高顺芝 罗兴章 |
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| 作者单位： | [1]嘉兴学院生物与化学工程学院,嘉兴314001 [2]嘉兴市化工清洁工艺重点实验室,嘉兴314001 [3]中石化苏州石油分公司,苏州215007 [4]复旦大学环境科学与工程系,上海200433 |
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| 基金项目： | 嘉兴市科技研究计划（2011AY1045）;嘉兴市化工清洁工艺重点实验室开放基金（8420900185）;嘉兴学院博士科研启动基金（70510007） |
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| 摘 要： | 采用生物淋滤法处理电子垃圾焚烧迹地重金属严重污染的土壤。所用氧化亚铁硫杆菌是从矿坑废水中通过一系列培养、分离和纯化得到。实验结果表明，生物淋滤法可以有效地去除土壤中重金属Cu、Ph和Zn，去除率的大小顺序为Zn〉Cu〉Pb；采用五步连续提取法分析处理前后土壤中重金属的存在形态，结果表明，通过氧化亚铁硫杆菌处理受重金属污染的土壤，可以促使易移动的重金属结合态的溶解（可交换态、碳酸盐结合态和Fe—Mn氧化物结合态），并使难移动的重金属结合态向易移动的重金属结合态转变。
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| 关 键 词： | 氧化亚铁硫杆菌 电子垃圾 重金属 生物浸出 |
Partitioning variation of heavy metals in contaminated soil by e-waste open burning activities via Thiobacillus Ferrooxidans bioleaching |
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| Zhao Guohua,＇,Gao Shunzhi,Luo Xingzhang.Partitioning variation of heavy metals in contaminated soil by e-waste open burning activities via Thiobacillus Ferrooxidans bioleaching[J].Techniques and Equipment for Environmental Pollution Control,2014(1):347-352. |
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| Authors: | Zhao Guohua ＇ Gao Shunzhi Luo Xingzhang |
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| Institution: | 4 (1. College of Biological and Chemical Engineering, Jiaxing University, Jiaxing 314001, China; 2. Key Laboratory of Clean Chemical Process of Jiaxing, Jiaxing 314001, China; 3. Sinopec Group, Suzhou 215007, China; 4. Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China) |
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| Abstract: | Metal removal by biological solubilization in strongly contaminated soil by e-waste open burning activities was carried out in shake flask experiments. Thiobacillus ferrooxidans isolated from coal mine water was used for bioleaching. The order of average solubilization efficiency of total extractable heavy metals was Zn 〉 Cu 〉 Pb. Variations in the binding forms of heavy metals were evaluated using a five-step sequential extraction pro- cedure before and after the bioleaching. The bioleaching process caused prompt solubilization of metals mostly as- sociated with the more labile fractions （exchangeable, carbonated and Fe-Mn oxide bound metals） , whereas those associated to the less labile ones （organic/residue fractions） were exchanged towards more labile fractions. The results of this study indicated that the bioleaching process can be useful for efficient removal of heavy metals from soil |
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| Keywords: | Thiobacillus ferrooxidans（ T f） e-waste heavy metals bioleaching |
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