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电混凝处理电镀综合废水
引用本文:王海东,陈发源,杨春风,赵旭,刘会娟,曲久辉.电混凝处理电镀综合废水[J].环境污染治理技术与设备,2013(10):3833-3838.
作者姓名:王海东  陈发源  杨春风  赵旭  刘会娟  曲久辉
作者单位:[1]中国科学院生态环境研究中心环境水质学国家重点实验室,北京100085 [2]河北工业大学土木工程学院,天津300401
基金项目:国家自然科学基金资助项目(51222802,21377148)
摘    要:采用电混凝法处理酸性电镀综合废水,首先研究了不同电流密度对总氰化物、重金属和化学需氧量(COD)去除率的影响。实验结果表明,电混凝可有效去除酸性电镀综合废水中的氰化物与重金属。随着电流密度的增大,总氰化物与重金属的去除率逐渐提高。当电流密度为10mA/cm2时,废水中残留的总氰化物、Cu2+、Ni2+、Cr6+和Zn2+ 的浓度分别为23.0、25.0、4.5、0.2和0.2mg/L。为了进一步提高去除率,在电化学体系中添加H2O2,随着H2O2投量的增大,总氰化物、重金属、COD去除率不断提高。当H2O2投量为3mL/L时,处理过废水中残留总氰化物、Cu2+、Ni2+、Cr6+、Zn2+和COD的浓度分别为0.2、2.0、3.0、1.5、0.1和220mg/L。

关 键 词:电镀综合废水  氰化物  重金属  电混凝

Treatment of electroplating wastewater by electrocoagulation
Wang Haidong,Chen Fayuan,Yang Chunfeng,Zhao Xu,Liu Huijuan,Qu Jiuhui.Treatment of electroplating wastewater by electrocoagulation[J].Techniques and Equipment for Environmental Pollution Control,2013(10):3833-3838.
Authors:Wang Haidong  Chen Fayuan  Yang Chunfeng  Zhao Xu  Liu Huijuan  Qu Jiuhui
Institution:1. State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eeo-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China; 2. School of Civil Engineering, Hebei University of Technology, Tianjin 300401, China)
Abstract:Treatment of an acid electroplating wastewater was performed by an electrocoagulation process firstly. Effect of current density and treatment time on the removal of total cyanide, heavy metals and COD was in- vestigated. The results showed that total cyanide and heavy metals can be efficiently removed by the electrocoagula- tion process, which increased with the current density. At a current density of 10 mA/cm2 , the residual total cya- nide, Cu2 + , Ni2+ , Cr6 + and Zn2 + were 23.0, 25.0, 4.5, 0.2 and 0.2 mg/L, respectively. Removal of COD by electrocoagulation process was limited. With addition of H2O2 to electrochemical system, the removal efficiency of the total cyanide and heavy metal and COD increased. With a H2O2 dose of 3 mL/L, the residual total cyanide, Cu2+ , Ni2+ , Cr6+ , Zn2+ and COD were 0.2, 2.0, 3.0, 1.5, 0.1 and 220 mg/L, respectively.
Keywords:electroplating wastewater  cyanide  heavy metal  electrocoagulation
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