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纳滤去除饮用水中的PFOS
引用本文:张健,赵长伟,宋娜,王涛,栾兆坤.纳滤去除饮用水中的PFOS[J].环境污染治理技术与设备,2013(11):4236-4240.
作者姓名:张健  赵长伟  宋娜  王涛  栾兆坤
作者单位:[1]中国科学院生态环境研究中心环境水质学国家重点实验室,北京100085 [2]中国矿业大学化学与环境工程学院,北京100083
基金项目:国家自然科学基金资助项目(21176245,50978245);“十二五”国家科技支撑计划项目(2012BAJ25802,2012BAJ125806)
摘    要:全氟辛烷磺酸类物质(PFOS)是一种新型持久性有机污染物,对人类健康存在很大威胁,目前世界范围内的水体中均检测到不同浓度的PFOS。研究如何安全有效去除这类新型污染物十分必要。利用HYDRA—COPe10纳滤膜进行PFOS去除研究,在不同操作压力下研究pH、电解质以及与腐殖酸共存对PFOS截留效果的影响。结果表明,随着pH值的增加,截留率上升;二价盐对PFOS截留率的影响要高于一价盐,并且随着二价盐离子强度的增加,截留率上升;腐殖酸共存时截留效率有显著增加,尤其在1mmol/L钙离子存在条件下,PFOS的截留率可达到95.8%,但会引起膜通量下降及膜污染的发生。

关 键 词:纳滤  PFOS  截留率  膜污染

Nanofiltration membrane process for removal of PFOS from drinking water
Zhang Jian,Zhao Changwei Song Na',Wang Tao Luan Zhaokun.Nanofiltration membrane process for removal of PFOS from drinking water[J].Techniques and Equipment for Environmental Pollution Control,2013(11):4236-4240.
Authors:Zhang Jian  Zhao Changwei Song Na'  Wang Tao Luan Zhaokun
Institution:1. State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China; 2. School of Chemical & Environmental Engineering, China University of Mining & Technology, Beijing 100083, China)
Abstract:Perfluorooctane sulfonate (PFOS) as one class of emerging pollutants detected from waters has drew great attention in recent years. How to remove PFOS from surface water and ensuring the security of drink- ing water for human beings is very important. In this study, HYDRA-core 10 nanofiltration membrane was used to remove PFOS from stimulate water, and the effects of operating pressure, pH, electrolytes, and humic acid on PFOS rejection were investigated. The results showed that the PFOS rejection increased with pH increase. The divalent salts could improve PFOS rejection compared with the monovalent salts, and the PFOS rejection in- creased with increasing ionic strength of divalent salts. The humic acid addition improved significantly PFOS re- jection, and it can reach up to 95.8% in the 1 mmol/L Ca2+ existence, but it would also cause membrane foul- ing and the decline of membrane flux.
Keywords:nanofiltration  PFOS  retention  membrane fouling
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