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Atmospheric concentrations, occurrence and deposition of persistent organic pollutants (POPs) in a Mediterranean coastal site (Etang de Thau, France)
Authors:Castro-Jiménez J  Mariani G  Vives I  Skejo H  Umlauf G  Zaldívar J M  Dueri S  Messiaen G  Laugier T
Institution:a European Commission-Joint Research Centre, Institute for Environment and Sustainability, via E. Fermi 2749, 21027 Ispra (VA), Italy
b European Commission-Joint Research Centre, Institute for Health and Consumer Protection, via E. Fermi 2749, 21027 Ispra (VA), Italy
c CRH, UMR 212 EME, Institut de Recherche pour le Développement, Avenue Jean Monnet BP 171, 34203 Sète Cedex, France
d Ifremer, Environment and Resources Laboratory, Avenue Jean Monnet BP 171, 34203 Sète Cedex, France
Abstract:Atmospheric concentrations and deposition fluxes of PCDD/F and PCB have been evaluated over a 1-year period in a Mediterranean coastal lagoon (Etang de Thau, France). Indicative PBDE air concentrations in the hot season are also reported in this work. ∑2,3,7,8-PCDD/Fs and ∑18PCBs (gas + particulate) air concentrations ranged from 67 to 1700 fg m−3 and from 13 to 95 pg m−3, respectively whereas ∑8PBDEs (gas + particulate) summer time levels varied from 158 to 230 pg m−3. The PCDD/F and PCB atmospheric occurrence over Thau lagoon and subsequent inputs to the surface waters are determined by an assemble of factors, being the seasonality of atmospheric concentration, the air mass origin and meteorological conditions important drivers. Total (wet + dry) ∑2,3,7,8-PCDD/Fs and ∑18PCBs deposition fluxes to Thau Lagoon waters are 117 and 715 pg m−2 d−1, respectively.
Keywords:PCDD/F  Dioxin-like PCB  PBDE  Air  Water
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