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表面活性剂强化超声波-离子液体预处理对水葫芦酶解的影响
引用本文:韩业钜,张耿崚,王小琴,陈细妹,邓昊,李清荷,刘敬勇,吕俊标,余华俭.表面活性剂强化超声波-离子液体预处理对水葫芦酶解的影响[J].环境科学学报,2017,37(7):2699-2706.
作者姓名:韩业钜  张耿崚  王小琴  陈细妹  邓昊  李清荷  刘敬勇  吕俊标  余华俭
作者单位:广东工业大学环境科学与工程学院和环境健康与污染控制研究院, 广州 510006,广东工业大学环境科学与工程学院和环境健康与污染控制研究院, 广州 510006,广东工业大学环境科学与工程学院和环境健康与污染控制研究院, 广州 510006,广东工业大学环境科学与工程学院和环境健康与污染控制研究院, 广州 510006,广东工业大学环境科学与工程学院和环境健康与污染控制研究院, 广州 510006,广东工业大学环境科学与工程学院和环境健康与污染控制研究院, 广州 510006,广东工业大学环境科学与工程学院和环境健康与污染控制研究院, 广州 510006,广东工业大学环境科学与工程学院和环境健康与污染控制研究院, 广州 510006,广东工业大学环境科学与工程学院和环境健康与污染控制研究院, 广州 510006
基金项目:广东工业大学青年基金(No.14QNZD005);广东工业大学青年百人A类项目(No.1143-220413105);广东省教育厅高等院校学科建设专项资金项目(No.2014KTSP022):资源综合利用与清洁生产重点实验室;广东工业大学研究生创新创业实践及竞赛项目(No.2016YJSCX034)
摘    要:为探讨表面活性剂对超声波-离子液体(US-IL)预处理木质纤维素的影响,本试验采用十二烷基硫酸钠(SDS)强化US-IL对水葫芦进行预处理,通过酶解、组成成分、表面形貌、结晶度以及化学结构的变化对预处理效果进行考察.结果显示,与未添加SDS相比,超声波-离子液体-十二烷基硫酸钠(US-IL-SDS)预处理能够有效降低纤维素的结晶度并去除木质素,酶解还原糖产量、纤维转化率及其脱木率分别提高72.23%、58.74%及21.01%.并且,SEM、XRD以及FTIR结果也表明SDS能够促进US-IL对水葫芦结构的破坏.因此,将SDS运用于辅助US-IL预处理木质纤维素具有一定可行性和良好的运用前景.

关 键 词:表面活性剂  超声波  离子液体  水葫芦  酶解  木质纤维素
收稿时间:2016/11/6 0:00:00
修稿时间:2016/12/15 0:00:00

Surfactant assisted ultrasound-ionic liquid pretreatment process for enzymatic hydrolysis of water hyacinth
HAN Yeju,CHANG Kenlin,WANG Xiaoqin,CHEN Ximei,DENG Hao,Potprommanee Laddawan,LIU Jingyong,Beel Liujim and YU Huajian.Surfactant assisted ultrasound-ionic liquid pretreatment process for enzymatic hydrolysis of water hyacinth[J].Acta Scientiae Circumstantiae,2017,37(7):2699-2706.
Authors:HAN Yeju  CHANG Kenlin  WANG Xiaoqin  CHEN Ximei  DENG Hao  Potprommanee Laddawan  LIU Jingyong  Beel Liujim and YU Huajian
Institution:School of Environmental Science and Engineering and Institute of Environmental Health and Pollution Control, Guangdong University of Technology, Guangzhou 510006,School of Environmental Science and Engineering and Institute of Environmental Health and Pollution Control, Guangdong University of Technology, Guangzhou 510006,School of Environmental Science and Engineering and Institute of Environmental Health and Pollution Control, Guangdong University of Technology, Guangzhou 510006,School of Environmental Science and Engineering and Institute of Environmental Health and Pollution Control, Guangdong University of Technology, Guangzhou 510006,School of Environmental Science and Engineering and Institute of Environmental Health and Pollution Control, Guangdong University of Technology, Guangzhou 510006,School of Environmental Science and Engineering and Institute of Environmental Health and Pollution Control, Guangdong University of Technology, Guangzhou 510006,School of Environmental Science and Engineering and Institute of Environmental Health and Pollution Control, Guangdong University of Technology, Guangzhou 510006,School of Environmental Science and Engineering and Institute of Environmental Health and Pollution Control, Guangdong University of Technology, Guangzhou 510006 and School of Environmental Science and Engineering and Institute of Environmental Health and Pollution Control, Guangdong University of Technology, Guangzhou 510006
Abstract:This study investigated the effects of surfactant (sodium dodecyl sulfate, SDS) in the lignocellulose pretreatment process with ultrasound-ionic liquid (US-IL) on the enzymatic hydrolysis efficiency, and the composition, morphology, crystalline and chemical structure of water hyacinth. The results show that the crystalline of cellulose and the lignin in biomass were cracked and removed effectively. Meanwhile, the production of reducing sugars, cellulose conversion and delignification increased by 72.23%, 58.74% and 21.01%, respectively. Moreover, SEM, XRD and FTIR analysis also demonstrate that the structure of the water hyacinth was destroyed by the ultrasound-ionic liquid-sodium dodecyl sulfate (US-IL-SDS) pretreatment. Overall, the novel pretreatment process with ultrasound-ionic liquid and surfactant had a great potential in lignocellulose disposal and reutilization.
Keywords:surfactant  ultrasound  ionic liquid  water hyacinth  enzymatic hydrolysis  lignocellulose
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