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管式反应器石灰雾液脱硫的数学模拟
引用本文:陆永琪,郝吉明,姚小红,周中平.管式反应器石灰雾液脱硫的数学模拟[J].环境科学学报,1999,19(6):636-641.
作者姓名:陆永琪  郝吉明  姚小红  周中平
作者单位:清华大学环境科学与工程系,北京,100084
摘    要:建立的一维管式反应器雾液脱硫模型是对蒸发和吸收过程的耦合,以膜理论为基础的吸收机理同时考虑了含硫组分的离解、扩散、反应和固体颗粒的溶解。参数敏感性分析表明,对系统脱硫率影响最显的是出口干湿球温差,石灰颗粒粒度和入口SO2浓度、传质过程的分析表明,反应开始阶段液膜扩散和固体溶解阻力均存在,而气膜扩散在整个反应过程中都起着重要作用。

关 键 词:雾化浆液  脱硫  模型  敏感性分析  传质
收稿时间:1998/1/21 0:00:00
修稿时间:1999/4/30 0:00:00

Mathematical modeling of SO2 removal with limespraysin atubularre actor
LU Yongqi,HAO Jiming,YAO Xiaohong and ZHOU Zhongping.Mathematical modeling of SO2 removal with limespraysin atubularre actor[J].Acta Scientiae Circumstantiae,1999,19(6):636-641.
Authors:LU Yongqi  HAO Jiming  YAO Xiaohong and ZHOU Zhongping
Institution:Dept.of Environ.Scienceand Eng., Tsinghua University, Beijing 100084,Dept.of Environ.Scienceand Eng., Tsinghua University, Beijing 100084,Dept.of Environ.Scienceand Eng., Tsinghua University, Beijing 100084 and Dept.of Environ.Scienceand Eng., Tsinghua University, Beijing 100084
Abstract:Amodeltosimulatethedesulfurizationofspraysinatubularreactor wasestablishedincombi nation withthe spray evaporation and SO2 absorption.Based on the film theory,theionization,diffusion and reaction ofsulfurconsitituents,andthedissolution oflimeparticulate wereconsideredintegrallyinthe model.Thesensitivity analysis of modelparametersshowed thattheefficiency of SO2 removalin such a system was highly dependentontheapproachtoadiabatictemperatureatexit,thesize ofsuspendedlime particulate andtheSO2concentrationinfluegas.Furthermore,thecalculation of masstransferrevealedthe obviousimportanceofgas film diffusion duringthe wholeprocedure,whiletheresistanceofliquidfilm and lime dissolution emerged only attheinitialstage ofabsorption.The model was proventoagree well with the experimentalresults with an averagerelativeerrorof8% .
Keywords:sprays  desulfurization  model  sensitivity analysis  masstransfer  
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