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硅氧烷在环境中的迁移转化及其对生物气应用的影响
引用本文:郑敏,吴唯民,迟莉娜,汪诚文.硅氧烷在环境中的迁移转化及其对生物气应用的影响[J].环境科学学报,2015,35(10):3050-3056.
作者姓名:郑敏  吴唯民  迟莉娜  汪诚文
作者单位:清华大学环境学院, 北京 100084,美国斯坦福大学土木与环境工程系, 科第伽资源回收研究中心 Stanford, CA94305, USA,上海交通大学环境科学与工程学院, 上海 200240,1. 清华大学环境学院, 北京 100084;2. 北京国环清华环境工程设计研究院有限公司, 北京 100084
基金项目:"十二五"国家科技支撑计划(No.2014BAC28B00)
摘    要:近年来大量使用含有机硅氧烷材料造成硅氧烷作为污染物进入环境,数量逐年增加.在垃圾填埋场和污水处理厂消化产生的生物气(沼气)中出现的硅氧烷会在燃烧过程中结垢,十分不利于生物气的利用,必须清除.本文综述了硅氧烷的理化性质、在环境中的迁移转化规律与生物降解性能、在生物气中的浓度分布以及去除技术,并对生物气应用中的硅氧烷的控制对策研究作出展望.作者强调,需进一步深入研究硅氧烷的生物降解的机理.

关 键 词:硅氧烷  生物气  迁移转化  浓度分布  去除技术
收稿时间:2014/10/15 0:00:00
修稿时间:2014/11/3 0:00:00

Distribution, migration and transformation of siloxanes in environment and its impact on biogas application
ZHENG Min,WU Weimin,CHI Lina and WANG Chengwen.Distribution, migration and transformation of siloxanes in environment and its impact on biogas application[J].Acta Scientiae Circumstantiae,2015,35(10):3050-3056.
Authors:ZHENG Min  WU Weimin  CHI Lina and WANG Chengwen
Institution:School of Environment, Tsinghua University, Beijing 100084,Department of Civil & Environmental Engineering, William & Cloy Codiga Energy Recovery Research Center, Stanford University, Stanford, CA 94305, USA,School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 and 1. School of Environment, Tsinghua University, Beijing 100084;2. Guohuan Tsinghua Environment Engineering Design & Research Institute Co., Ltd., Beijing 100084
Abstract:Siloxane has become an environmental concern as poly-dimethylsiloxanes are extensively applied. Siloxanes in biogas generated from landfill and anaerobic digestion at wastewater treatment plants must be removed before the biogas is used for electricity generation in case of production of silicon precipitates inside an engine. This paper reviews the updated research results on siloxanes including physical-chemical properties, contaminant sources, migration and transformation in environment, biodegradability, concentration profile in biogas, and current technologies for siloxane removal. The topics of future study are discussed, focusing on mechanism of biodegradation and microbiology.
Keywords:siloxane  biogas  migration and transformation  concentration profile  removal technology
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