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US/UV协同催化氧化降解对氯苯酚的研究
引用本文:赵德明,史惠祥,雷乐成,汪大翚.US/UV协同催化氧化降解对氯苯酚的研究[J].环境科学学报,2003,23(5):588-592.
作者姓名:赵德明  史惠祥  雷乐成  汪大翚
作者单位:1. 浙江大学,玉泉校区,环境工程系,杭州,310027;浙江工业大学化工与材料学院
2. 浙江大学,玉泉校区,环境工程系,杭州,310027
基金项目:国家自然科学基金资助项目 (编号 :2 0 176 0 5 3)
摘    要:选择掺杂过渡金属离子Fe^3 的纳米TiO2为催化剂,研究了US(超声波)/UV(紫外光)协同催化氧化水中对氯苯酚(4-CP)的降解效果,考察了对氯苯酚的起始浓度、超声波声强、溶液初始pH、饱和气体种类、反应温度和催化剂投加量对氯苯酚降解速率的影响.研究结果表明:US/UV协同催化氧化处理比单独超声波处理和光化学处理,4-CP降解速率提高了1.5~1.7倍,证实了声光联合技术具有明显的协同效应.

关 键 词:US/UV协同催化氧化  降解  苯酚  纳米TiO2  超声波  水污染  污染控制
文章编号:0253-2468(2003)05-0588-05
收稿时间:2002/11/24 0:00:00
修稿时间:2002年11月24

Degradation of 4-Chlorophenol in wastewater by US/UV synergetic catalysis technology
ZHAO Deming,SHI Huixiang,LEI Lecheng and WANG Dahui.Degradation of 4-Chlorophenol in wastewater by US/UV synergetic catalysis technology[J].Acta Scientiae Circumstantiae,2003,23(5):588-592.
Authors:ZHAO Deming  SHI Huixiang  LEI Lecheng and WANG Dahui
Institution:1. Department of Environmental Engineering, Zhejiang University, Hangzhou 310027, China; 2. College of Chemical Engineering and Materal, Zhejiang University of Technoligy,Department of Environmental Engineering, Zhejiang University, Hangzhou 310027, China,Department of Environmental Engineering, Zhejiang University, Hangzhou 310027, China and Department of Environmental Engineering, Zhejiang University, Hangzhou 310027, China
Abstract:Chlorophenol (4-CP) solution was treated by US(Ultrasound)/UV(Ultraviolet) synergetic catalysis technology and the major influencing factors such as the sound intensity, initial pH value of solution, initial 4-CP concentration, the amount of catalyst and medium temperature were examined in this paper. The results showed that that US/UV synergetic technology was superior to each of ultrasound irradiation and photochemistry alone. Within half an hour, the sum of 4-CP removal rates by as using ultrasound irradiation and photochemistry respectively to degrade 4-CP was obviously less than the removal rate by using US/UV synergetic technology. The significant synergetic effect of US/UV was identified.
Keywords:Chlorophenol (4-CP)  US(Ultrasound)/UV(Ultraviolet)  catalyst  synergetic effect
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