多菌灵的光化学降解研究

以太阳光和高压汞为灯光源研究了多菌灵在溶液相中的光化学降解：在太阳光下，多菌灵在甲醇，正已烷、重蒸水、３种ＰＨ缓冲液和不同类型水质中光稳定性很强，但在丙酮中可以光解，光 解半衰期为３３．８０ｈ光敏剂核黄素、０．５％内酮、ｅ＾３＋能加快多菌灵在水溶中的光解速率，其中黄素敏化效果最显著，说明在太阳光下多菌灵在水溶液中主要是间接光解，与太阳光源比较，多菌灵在高汞灯下主要进行直接光解，在重蒸水中的光钐半衰

Studies on photodegradation of carbendazim in solvents and aqueous solutions

Under sunlight or high pressure mercury lamp(HPML),the phototransformation of carbendazim in solvents and aqueous solutions was studied.The main results were summarized as follows:Carbendazim decomposed very slowly in aqueous phase, n \|hexane and methanol under sunlight.The photolytic rate of MBC in acetone was high with half\|life of 33.80?h.Photosensitizer such as riboflavin,0 5% acetone and Fe 3 ,can enhance photolysis of MBC in aqueous solutions.Among them,riboflavin is the most senstivive one MBC can be degraded by 53 47% after 16 hours.Three pesticides,namely,triadimefon,butachlor,and carbofuran can affected significantly the photodecomposition of MBC in water under HPML.By 2 hours irradiation,the photoquench efficiency of triadimefon,butachlor and carbofuran on cabendazim are 244 05%,252 81%,and 262 92%,respectively.Under HPML,direct photolysis is the main process.The half\|life in redistilled water is 74 62?min.The photolytic rates of carbendazim in different water types or pH show following sequence:redistilled water>river water>pond water,or,pH4>pH9>pH7.