| 真菌预处理优化制备微介多级孔炭及其吸附甲苯的研究 |
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| 引用本文： | 张伟霞,黄春蕾,柯云婷,张琪,邹思贝,付名利,黄皓旻,叶代启.真菌预处理优化制备微介多级孔炭及其吸附甲苯的研究[J].环境科学学报,2018,38(10):3917-3926. |
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| 作者姓名： | 张伟霞 黄春蕾 柯云婷 张琪 邹思贝 付名利 黄皓旻 叶代启 |
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| 作者单位： | 华南理工大学环境与能源学院;挥发性有机物污染治理技术与装备国家工程实验室;广东省大气环境与污染控制重点实验室;广东省环境风险防控与应急处置工程技术研究中心 |
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| 基金项目： | 广东省自然科学基金博士启动项目（No.2017A030310537）；国家自然科学基金（No.51578245）；国家重点研发计划（No.2016YFC0204203）；广州市科技计划项目（No.201804020026）；中央高校基本科研业务费（No.2017BQ07） |
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| 摘 要： | 提出采用黄孢原毛平革菌对生物质前体物进行预处理的制备策略,从而研发孔结构可调的多级孔炭材料模板.选用荷叶作为生物质原材料,探讨菌种投加量、培养时间对多级孔炭材料前驱体的影响,并采用水蒸气物理活化法,分析活化温度和活化时间对炭材料比表面积、孔径分布和表面官能团的综合作用.最后,通过Raman、XRD、BET、FTIR、TGA、SEM、EA等手段表征其物理化学性质,并考察真菌预处理对炭材料的甲苯吸附性能的影响.结果表明,在生物质荷叶质量30 g、菌种投加量4 mL、培养时间7 d、活化温度800℃、活化时间90 min条件下制备的微介多级孔炭材料,在含有较多介孔的前提下比表面积可达937 m~2·g~(-1),总孔容为0.68 cm~3·g~(-1).动态模拟吸附实验发现,经预处理的炭材料在甲苯浓度905 mg·m~(-3)下对其饱和吸附容量为304 mg·g~(-1),是未经真菌调控荷叶吸附容量的1.83倍,吸附性能的提升主要归因于比表面积、孔容及表面酸性基团增大的作用.经真菌预处理调控的炭材料对甲苯的吸附符合Langmuir吸附等温线,属于单分子层吸附.
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| 关 键 词： | 微介多级孔炭材料 黄孢原毛平革菌 调控 木质素 甲苯 |
| 收稿时间： | 2018/3/12 0:00:00 |
| 修稿时间： | 2018/5/29 0:00:00 |
Preparation of Phanerochaete chrysosporium modified micro-meso hierarchical porous carbon and its adsorption performance for toluene |
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| ZHANG Weixi,HUANG Chunlei,KE Yunting,ZHANG Qi,ZOU Sibei,FU Mingli,HUANG Haomin and YE Daiqi.Preparation of Phanerochaete chrysosporium modified micro-meso hierarchical porous carbon and its adsorption performance for toluene[J].Acta Scientiae Circumstantiae,2018,38(10):3917-3926. |
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| Authors: | ZHANG Weixi HUANG Chunlei KE Yunting ZHANG Qi ZOU Sibei FU Mingli HUANG Haomin and YE Daiqi |
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| Institution: | School of Environment and Energy, South China University of Technology, Guangzhou 510006,School of Environment and Energy, South China University of Technology, Guangzhou 510006,School of Environment and Energy, South China University of Technology, Guangzhou 510006,School of Environment and Energy, South China University of Technology, Guangzhou 510006,School of Environment and Energy, South China University of Technology, Guangzhou 510006,1. School of Environment and Energy, South China University of Technology, Guangzhou 510006;2. National Engineering Laboratory for VOCs Pollution Control Technology and Equipment, Guangzhou 510006;3. Guangdong Provincial Key Laboratory of Atmospheric Environment and Pollution Control(SCUT), Guangzhou 510006;4. Guangdong Provincial Engineering and Technology Research Centre for Environmental Risk Prevention and Emergency Disposal, South China University of Technology, Guangzhou 510006,1. School of Environment and Energy, South China University of Technology, Guangzhou 510006;2. National Engineering Laboratory for VOCs Pollution Control Technology and Equipment, Guangzhou 510006;3. Guangdong Provincial Key Laboratory of Atmospheric Environment and Pollution Control(SCUT), Guangzhou 510006;4. Guangdong Provincial Engineering and Technology Research Centre for Environmental Risk Prevention and Emergency Disposal, South China University of Technology, Guangzhou 510006 and 1. School of Environment and Energy, South China University of Technology, Guangzhou 510006;2. National Engineering Laboratory for VOCs Pollution Control Technology and Equipment, Guangzhou 510006;3. Guangdong Provincial Key Laboratory of Atmospheric Environment and Pollution Control(SCUT), Guangzhou 510006;4. Guangdong Provincial Engineering and Technology Research Centre for Environmental Risk Prevention and Emergency Disposal, South China University of Technology, Guangzhou 510006 |
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| Abstract: | |
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| Keywords: | micro-meso hierarchical porous carbon Phanerochaete chrysosporium modification lignin toluene |
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