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均相表面扩散模型(HSDM)在活性炭吸附去除水中典型嗅味物质中的应用
引用本文:赵艳梅,于建伟,郑红,杨敏,郭召海,张利田.均相表面扩散模型(HSDM)在活性炭吸附去除水中典型嗅味物质中的应用[J].环境科学学报,2007,27(12):1944-1950.
作者姓名:赵艳梅  于建伟  郑红  杨敏  郭召海  张利田
作者单位:1. 中国科学院生态环境研究中心环境水质学国家重点实验室,北京,100085;中国地质大学材料科学与工程学院,北京,100083
2. 中国科学院生态环境研究中心环境水质学国家重点实验室,北京,100085
3. 中国地质大学材料科学与工程学院,北京,100083
基金项目:国家自然科学基金 , 北京市科委重大项目
摘    要:水厂中投加粉末活性炭时,由于反应时间非常短,其吸附动力学行为的确定非常重要.利用均相表面扩散模型(HSDM)对粉末活性炭吸附水中2-甲基异莰醇(MIB)及土臭素(geosmin)时的动力学过程进行了模拟.结果表明,只要通过1组吸附动力学实验取得相应的数据,就可以利用均相表面扩散模型HSDM对不同投量下粉末活性炭的吸附动力学过程进行有效的预测,并结合原水中MIB或geosmin的初始浓度、需要处理达到的目标浓度以及粉末活性炭接触时间,确定粉末活性炭的投加量.

关 键 词:均相表面扩散模型  粉末活性炭  吸附动力学  2-甲基异莰醇  土臭素  表面  扩散模型  活性  炭吸附  除水  嗅味物质  应用  diffusion  model  surface  homogeneous  Application  powdered  activated  carbon  water  compounds  odor  typical  投加量  接触时间  初始浓度  目标
文章编号:0253-2468(2007)12-1944-07
收稿时间:2007-10-09
修稿时间:2007-10-12

Application of homogeneous surface diffusion model (HSDM) to the removal of typical odor compounds in water by powdered activated carbon
ZHAO Yanmei,YU Jianwei,ZHENG Hong,YANG Min,GUO Zhaohai and ZHANG Litian.Application of homogeneous surface diffusion model (HSDM) to the removal of typical odor compounds in water by powdered activated carbon[J].Acta Scientiae Circumstantiae,2007,27(12):1944-1950.
Authors:ZHAO Yanmei  YU Jianwei  ZHENG Hong  YANG Min  GUO Zhaohai and ZHANG Litian
Institution:1. State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085; 2. School of Materials Science and Technology, China University of Geosciences, Beijing 100083,State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085,School of Materials Science and Technology, China University of Geosciences, Beijing 100083,State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085,State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085 and State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085
Abstract:Because of the short contact time,it is important to determine the adsorption kinetics of powdered activated carbon(PAC) on applying PAC in waterworks.In this study,the application of homogeneous surface diffusion model(HSDM) to the prediction of removal kinetics of MIB and geosmin was introduced.It was found that the kinetic processes under different PAC doses could be predicted with HSDM through only one set of kinetic experiment.It is possible to predict the dosage of PAC with HSDM,if the concentration of the target compounds,the contact time of PAC in waterworks,and the treatment target are determined.
Keywords:homogeneous surface diffusion model(HSDM)  powdered activated carbon  adsorption kinetics  2-methylisobornel(MIB)  geosmin
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