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混凝研究中的界面过程化学:IPF-颗粒物-水溶液的相互作用
引用本文:王东升,陈有军,孙伟,王震.混凝研究中的界面过程化学:IPF-颗粒物-水溶液的相互作用[J].环境科学学报,2003,23(2):178-182.
作者姓名:王东升  陈有军  孙伟  王震
作者单位:中国科学院生态环境研究中心环境水质学国家重点实验室,北京,100085
基金项目:国家自然科学基金资助 ( 5 0 0 780 5 1)
摘    要:仅以IPF 颗粒物 水溶液的相互作用为例 ,对混凝研究中二界面过程化学领域的进展加以介绍 .研究结果表明 ,经过预制的聚合铝在混凝过程中表现出较好的形态稳定性 ,而传统混凝剂则强烈地受溶液化学过程 ,尤其是溶液pH值的影响 .混凝剂水解聚合形态倾向于在颗粒物表面吸附沉积 ,而直接引发混凝作用 .单体形态则通过转化为聚合、沉淀形态起混凝作用

关 键 词:混凝  界面化学  无机高分子絮凝剂(IPF)  水体颗粒物  溶液化学
文章编号:0253-2468(2003)02-0178-05
收稿时间:2002/7/10 0:00:00
修稿时间:2002年7月10日

Interfacial process chemistry in coagulation:interaction of IPF-particle-aqueous solution
WANG Dongsheng,CHEN Youjun,SUN Wei and WANG Zhen.Interfacial process chemistry in coagulation:interaction of IPF-particle-aqueous solution[J].Acta Scientiae Circumstantiae,2003,23(2):178-182.
Authors:WANG Dongsheng  CHEN Youjun  SUN Wei and WANG Zhen
Institution:SKLEAC, Res.Center for Eco-Envir. Sci., Academia Sinica, Beijing 100085,SKLEAC, Res.Center for Eco-Envir. Sci., Academia Sinica, Beijing 100085,SKLEAC, Res.Center for Eco-Envir. Sci., Academia Sinica, Beijing 100085 and SKLEAC, Res.Center for Eco-Envir. Sci., Academia Sinica, Beijing 100085
Abstract:The interfacial process chemistry of the aquatic particle, which forms an important content and theoretical basis for the research and development of coagulation technique, plays a significant role during coagulation process. The interation of inorganic polymer flocculant(IPF)-particle-aqueous solution was discussed as an example. The experimental results showed that the pre-formed PACl exhibits relative speciation stability during coagulation, while the traditional metal salts are affected strongly by the solution chemical processes, especially the pH. The hydrolyzed species adsorb and deposit strongly on the particle interface,which causes the coagulation. The monomer species coagulate particles through transformation into polymeric and colloidal species.
Keywords:coagulation  interface chemistry  inorganic polymer flocculant  aquatic particle  solution chemistry
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