| 上海市大气散射消光特征及其与颗粒物化学组成关系研究 |
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| 引用本文： | 徐薇,修光利,陶俊,王丽娜,朱梦雅,黄众思,蔡婧,乔婷,张大年.上海市大气散射消光特征及其与颗粒物化学组成关系研究[J].环境科学学报,2015,35(2):379-385. |
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| 作者姓名： | 徐薇 修光利 陶俊 王丽娜 朱梦雅 黄众思 蔡婧 乔婷 张大年 |
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| 作者单位： | 国家环境保护化工过程环境风险评价与控制重点实验室, 华东理工大学, 上海 200237;国家环境保护化工过程环境风险评价与控制重点实验室, 华东理工大学, 上海 200237;环保部华南环境科学研究所, 广州 510655;国家环境保护化工过程环境风险评价与控制重点实验室, 华东理工大学, 上海 200237;国家环境保护化工过程环境风险评价与控制重点实验室, 华东理工大学, 上海 200237;国家环境保护化工过程环境风险评价与控制重点实验室, 华东理工大学, 上海 200237;国家环境保护化工过程环境风险评价与控制重点实验室, 华东理工大学, 上海 200237;国家环境保护化工过程环境风险评价与控制重点实验室, 华东理工大学, 上海 200237;国家环境保护化工过程环境风险评价与控制重点实验室, 华东理工大学, 上海 200237 |
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| 基金项目： | 国家环境保护公益性行业科研专项(No.200809143);国家自然科学基金(No.21277044);上海市教委科研创新基金(No.12ZZ054);中央高校科研经费(No.WB1113005) |
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| 摘 要： | 为研究上海市大气颗粒物散射系数分布特征以及颗粒物化学组分贡献率,2009年用浊度仪对散射系数进行观测,同时采集PM2.5,分析其主要化学成分浓度.观测发现,秋、冬季散射系数较高,夏季最小.散射系数日变化有早、晚两个峰,午间出现低谷.散射系数与温度、风速有显著负相关性.多元回归得到OC、NO-3、NH+4是影响消光系数的主要化学成分.依据IMPROVE估算公式,将OC分为吸湿性和非吸湿性部分,并加入海盐影响,使估算bext值更接近监测值.OC、EC和硫酸铵盐为估算消光系数主要贡献成分.
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| 关 键 词： | 散射系数 PM2.5 能见度 化学组分 |
| 收稿时间： | 2014/4/22 0:00:00 |
| 修稿时间： | 2014/6/27 0:00:00 |
Characterization of light scattering extinction and the relationship with particle components in Shanghai |
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| XU Wei,XIU Guangli,TAO Jun,WANG Lin,ZHU Mengy,HUANG Zhongsi,CAI Jing,QIAO Ting and ZHANG Danian.Characterization of light scattering extinction and the relationship with particle components in Shanghai[J].Acta Scientiae Circumstantiae,2015,35(2):379-385. |
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| Authors: | XU Wei XIU Guangli TAO Jun WANG Lin ZHU Mengy HUANG Zhongsi CAI Jing QIAO Ting and ZHANG Danian |
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| Institution: | State Environmental Protection Key Laboratory of Risk Assessment and Control on Chemical Processes, East China University of Science and Technology, Shanghai 200237;State Environmental Protection Key Laboratory of Risk Assessment and Control on Chemical Processes, East China University of Science and Technology, Shanghai 200237;Ministry of South China Environmental Science Research Institute, Guangzhou 510655;State Environmental Protection Key Laboratory of Risk Assessment and Control on Chemical Processes, East China University of Science and Technology, Shanghai 200237;State Environmental Protection Key Laboratory of Risk Assessment and Control on Chemical Processes, East China University of Science and Technology, Shanghai 200237;State Environmental Protection Key Laboratory of Risk Assessment and Control on Chemical Processes, East China University of Science and Technology, Shanghai 200237;State Environmental Protection Key Laboratory of Risk Assessment and Control on Chemical Processes, East China University of Science and Technology, Shanghai 200237;State Environmental Protection Key Laboratory of Risk Assessment and Control on Chemical Processes, East China University of Science and Technology, Shanghai 200237;State Environmental Protection Key Laboratory of Risk Assessment and Control on Chemical Processes, East China University of Science and Technology, Shanghai 200237 |
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| Abstract: | This study aims to investigate the characteristics of scattering coefficients of particle distribution and the contribution of different chemical components in Shanghai. We used nephelometer to measure scattering coefficients in 2009. PM2.5 was sampled and their chemical compositions were analyzed simultaneously. The results showed that scattering coefficients were high in fall and winter and low in summer. The diurnal variation displayed bimodal distribution in the morning and at night, respectively, and a though in the afternoon. The observed scattering coefficients were negatively significantly correlated with temperature and wind speed. EC, NO3- and NH4+ were identified as the primary components responsible for extinction coefficient by means of multiple regression models. By separating OC into hygroscopic and non-hygroscopic parts and taking into consideration the role of sea salt ion concentration in the IMPROVE formula, we reached more accurate estimates of bext values. Furthermore, OC, EC and ammonium sulfate were the main components to estimate scattering coefficients. |
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| Keywords: | scattering coefficients PM2 5 visibility components |
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