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活性炭间歇式吸附亚甲基蓝废水的研究
引用本文:方雪坤,胡宏,吴顺志.活性炭间歇式吸附亚甲基蓝废水的研究[J].能源环境保护,2008,22(6):29-32.
作者姓名:方雪坤  胡宏  吴顺志
作者单位:1. 浙江大学环境与资源学院,浙江杭州,310029
2. 煤炭科学研究总院杭州环境保护研究所,浙江杭州,311200
摘    要:以亚甲基蓝(MB)作为模拟染料废水,系统考察了活性炭(AC)对亚甲基蓝的吸附性能。计算得到了△G^0、△H^0、△S^0等几个热力学参数。实验结果表明:活性炭的吸附性能取决于吸附时间、废水pH值和废水温度。吸附行为符合二级反应速率方程所描述的规律和Langmuir吸附等温式。废水pH值的升高有利于提高最终吸附处理的效果。活性炭对亚甲基蓝的吸附是一个自发的、弱吸热的物理过程,温度的升高有利于吸附的进行。

关 键 词:吸附  活性炭  亚甲基蓝  吸附时间  PH  温度

STUDY ON THE INTERMISSIVE ADSORPTION OF METHYLENE BLUE IN DYESTUFF WASTEWATER BY ACTIVATED CARBON
FANG Xue-kun,HU Hong,WU Shun-zhi.STUDY ON THE INTERMISSIVE ADSORPTION OF METHYLENE BLUE IN DYESTUFF WASTEWATER BY ACTIVATED CARBON[J].Energy Environmental Protection,2008,22(6):29-32.
Authors:FANG Xue-kun  HU Hong  WU Shun-zhi
Institution:FANG Xue- kun, HU Hong,WU Shun- zhi ( 1. College of Environmental and Resource Science, Zhejiang University, Hangzhou 310029, China; 2. Hangzhou Environmental Protection Research Institute, CCRI, Hangzhou 311201, China)
Abstract:The adsorption capacity of methylene blue in wastewater by activated carbon was measured, thus having systematically studied the Property about the intermissive adsorption of methylene blue. The thermodynamic parameters such as △G^0、△H^0 and △S^0 have been calculated. The results show that the property of adsorption depends on adsorption time,pH and temperature. The adsorption of activated carbon for Methylene Blue fits well with the pseudo - second - rate equation and Langmuir isotherm model. The higher pH of dyestuff wastewater is, the better treatment effect can be obtained. Meanwhile, the adsorption of activated carbon for Methylene is a spontaneously and endothermically physical process, temperature increases being beneficial to adsorption.
Keywords:pH
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