| 共振散射光谱法测定部分水解聚丙烯酰胺的水解度 |
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| 引用本文： | 凌绍明.共振散射光谱法测定部分水解聚丙烯酰胺的水解度[J].环境工程,2011(Z1). |
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| 作者姓名： | 凌绍明 |
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| 作者单位： | 百色学院化学与生命科学系; |
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| 摘 要： | 在1.0 mol/L醋酸介质中,部分水解聚丙烯酰胺(HPAM)与次氯酸钠溶液作用生成疏水性的氯酸胺微粒,该微粒体系在480nm处产生强的共振散射峰。HPAM的酰胺基团浓度在1.12~56.0 mg/L范围内与480nm处共振散射光强度成线性关系,检出限为0.21 mg/L。研究了共存物质对共振散射光谱法测定HPAM酰胺基浓度的影响,该方法的选择性较好,应用于样品中HPAM水解度的测定,结果满意。
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| 关 键 词： | 部分水解聚丙烯酰胺 水解度 共振散射光谱法 次氯酸钠 |
DETERMINING HYDROLYSIS DEGREE OF HPAM POLYMERS BY RESONANCE SCATTERING SPECTRAL METHOD |
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| Ling Shaoming.DETERMINING HYDROLYSIS DEGREE OF HPAM POLYMERS BY RESONANCE SCATTERING SPECTRAL METHOD[J].Environmental Engineering,2011(Z1). |
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| Authors: | Ling Shaoming |
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| Institution: | Ling Shaoming(Depertment of Chemistry and Life Science,Baise University,Baise 533000,China) |
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| Abstract: | In the medium of HAc,partially hydrolyzed polyacrylamides(HPAM) reacted with NaClO to form ammonia chlorate nanoparticles,which were hydrophobic and had a strong resonance scattering(RS) peak at 480 nm.The RS intensity at 480 nm(I480nm) increased linearly to the amide group content in the range of 1.12~56.0 mg/L,and the detection limit was 0.21mg/L.The effect of coexistent substances on the determination of PAM was studied,and it showed this RS method has good selectivity.The hydrolysis degree of HPAM in sa... |
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| Keywords: | partially hydrolyzed polyacrylamides(HPAM) hydrolysis degree resonance scattering spectral method sodium hypochlorite |
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