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固体云爆剂热分解性能研究
引用本文:石腾飞,陈明华,樊义伟,刘海涛.固体云爆剂热分解性能研究[J].装备环境工程,2017,14(1):18-20.
作者姓名:石腾飞  陈明华  樊义伟  刘海涛
作者单位:1. 军械工程学院弹药工程系,石家庄,050003;2. 军械技术研究所,石家庄,050000;3. 晋西工业集团江阳公司,太原,030041
摘    要:目的研究固体云爆剂的热分解特性。方法利用差示扫描量热(DSC)和热重分析(TG)测定该固体云爆剂的热分解过程。分别得到固体云爆剂在不同温度下的DSC和TG曲线,以及同一温度下云爆剂不同组分的DSC和TG曲线。结合线性回归分析的方法,利用Ozawa法、Starink法以及Kissinger法计算了反应活化能。结果其表观活化能为208 k J/mol左右。结论该固体云爆剂的热分解是一个连续的过程,具有良好的安定性。

关 键 词:固体云爆剂  热分解  反应活化能
收稿时间:2016/7/21 0:00:00
修稿时间:2017/1/15 0:00:00

Thermal Decomposition Performance of SE-FAE
SHI Teng-fei,CHEN Ming-hu,FAN Yi-wei and LIU Hai-tao.Thermal Decomposition Performance of SE-FAE[J].Equipment Environmental Engineering,2017,14(1):18-20.
Authors:SHI Teng-fei  CHEN Ming-hu  FAN Yi-wei and LIU Hai-tao
Institution:Ammunition Engineering Department of Ordnance Engineering College, Shijiazhuang 050000, China,Ordnance Technology Research Institute, Shijiazhuang 050000, China,Jiangyang Company, Jinxi Industrial Group, Taiyuan 030041, China and Ordnance Technology Research Institute, Shijiazhuang 050000, China
Abstract:Objective To research thermal decomposition characteristics of SE-FAE.Methods The thermal decomposition process of SE-FAE was analyzed by Differential Scanning Calorimetry (DSC) and Thermo Gravimetric (TG) analysis.DSC and TG curves of SE-FAE at different temperature as well as DSC and TG curves of different components at the same temperature were obtained.The reaction activation energy was calculated through Ozawa,Starink and Kissinger methods in combination with linear-regression analysis.Results Its apparent activation energy was about 208 kJ·mol-1.Conclusion Thermal decomposition of SE-FAE is a continuous process of good stability.
Keywords:SE-FAE  thermal decomposition  reaction activation energy
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