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插层改性累托石对水性环氧涂料性能的影响
引用本文:冯全芬,李浙华,郝龙,林安,甘复兴.插层改性累托石对水性环氧涂料性能的影响[J].装备环境工程,2007,4(2):7-10.
作者姓名:冯全芬  李浙华  郝龙  林安  甘复兴
作者单位:1. 武汉大学资源与环境学院环境工程系,武汉,430079
2. 湖北君邦环境技术有限责任公司,武汉,430022
3. 武汉大学资源与环境学院环境工程系,武汉,430079;金属腐蚀与防护国家重点实验室,沈阳,110016
摘    要:根据累托石可进行阳离子交换的矿物学特征,先将天然累托石钠基化,再用氟碳表面活性剂和复合季铵盐对其进行插层改性,使有机铵阳离子进入累托石层间,并使层间距由2.41nm撑开至4.75nm,将插层改性后的累托石用作水性环氧涂料的防沉剂和流变助剂.结果表明:当插层改性累托石用量为颜填料质量的2%时,可以显著改善涂料的流平性、抗流挂性和颜填料的分散性.

关 键 词:累托石  插层改性  流平性  抗流挂性  分散性  改性累托石  水性环氧涂料  涂料性能  影响  Coatings  Epoxy  Rectorite  Modified  分散性  流挂性  流平性  改善  质量  颜填料  用量  结果  流变助剂  防沉剂  间距  阳离子
文章编号:1672-9242(2007)02-0007-04
修稿时间:2007-01-28

Effect of Layer-inserting Modified Rectorite on Water-born Epoxy Coatings
FENG Quan-fen,LI Zhe-hua,HAO Long,LIN An,GAN Fu-xing.Effect of Layer-inserting Modified Rectorite on Water-born Epoxy Coatings[J].Equipment Environmental Engineering,2007,4(2):7-10.
Authors:FENG Quan-fen  LI Zhe-hua  HAO Long  LIN An  GAN Fu-xing
Institution:1. Wuhan University, Wuhan 430072, China ; 2. Hubei Gambol Environmental Technology Co. Ltd., Wuhan 430022; 3. State Key Laboratory for Corrosion and Protection Metals, Shenyang 110016, China
Abstract:According to the cation-exchange mineral characters,rectorite was first sodium-ionized modified,and then inserting-layer modified by fluorocarbon surfactant and complex quaternary ammonium salt.Organic ammonium cation enters into the layers of rectorite and makes the interlayer spacing grow from 2.41nm to 4.75nm.The modified rectorite can be used as anti-setting agent and dispersant of water-borne epoxy coatings.The results showed that when the additive mass of modified rectorite is 2% of the fillers,the characters of leveling,anti-sagging,and dispersibility of the coatings can be improved obviously.
Keywords:rectorite  layer-inserting  leveling  anti-sagging  dispersibility
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