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空气注入原位去除鸡粪发酵沼气中H2S
引用本文:宋云龙,Ahmed Mahdy,乔玮,董仁杰.空气注入原位去除鸡粪发酵沼气中H2S[J].中国环境科学,2020,40(2):688-694.
作者姓名:宋云龙  Ahmed Mahdy  乔玮  董仁杰
作者单位:中国农业大学工学院, 国家能源生物燃气高效制备及综合利用技术研发实验中心, 北京 100083
基金项目:北京市自然科学基金(6182017)
摘    要:鸡粪厌氧发酵产沼气中H2S含量高,在发电或提纯制备生物燃气前需要对其进行去除.开展批次鸡粪发酵试验,向发酵瓶中通入微量空气,通过生物氧化作用去除H2S.试验以连续稳定运行90d的中温厌氧罐出料为接种污泥,通入7~50mL/gVS的空气.结果表明,空气通入显著地降低了沼气中的H2S浓度,空气通入量为30mL/gVS的实验组平均脱硫效率最高,达到62%.同时,该空气通入条件下累积甲烷产量达到335mL/gVS,相较于空白累积甲烷产量提升了78.6%.通入微量空气的生物脱硫方法具有工艺简单和高效脱除H2S的应用前景.

关 键 词:鸡粪  厌氧发酵  微氧法  生物脱硫  
收稿时间:2019-07-02

In-situ removal of H2S from chicken manure biogas by injecting air
SONG Yun-long,Ahmed Mahdy,QIAO Wei,DONG Ren-jie.In-situ removal of H2S from chicken manure biogas by injecting air[J].China Environmental Science,2020,40(2):688-694.
Authors:SONG Yun-long  Ahmed Mahdy  QIAO Wei  DONG Ren-jie
Institution:Research&Development Center for Efficient Production and Comprehensive Utilization of Biobased Gaseous Fuels, Energy Authority, National Development and Reform Committee, College of Engineering, China Agricultural University, Beijing 100083, China
Abstract:Biogas from chicken manure with anaerobic digestion has a high concentration of H2S, which needs to be removed before further utilization such as power generation or purification to produce bio-natural gas. A batch experiment of chicken manure digestion was carried out in this study, and trace amount of air was introduced into the reactors to remove hydrogen sulfide by biological oxidation. The test was carried out by feeding the inoculum obtained from the effluent of chicken manure methane digestion reactor under mesophilic conditions, and introducing air at level of 7~50mL/g VS. Air introduction significantly reduces the H2S concentration in the biogas. The experimental group with an air dosage of 30mL/g VS had the highest average desulfurization efficiency of 62%. At the same time, the cumulative methane production of the experimental group with an air dosage of 30mL/gVS reached 335mL/gVS, which was 78.6% higher than the control group. The biological desulfurization method with trace amount of oxygen has the application prospect of simple procedure and efficient removal of H2S.
Keywords:chicken manure  anerobic digestion  micro-aeration  biological desulfurization  
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