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三种土壤中土霉素浸提方法的比较研究
引用本文:余强,鲍艳宇,李艳梅,周启星,刘雨霞.三种土壤中土霉素浸提方法的比较研究[J].中国环境科学,2011,31(6):951-957.
作者姓名:余强  鲍艳宇  李艳梅  周启星  刘雨霞
作者单位:1. 南开大学环境科学与工程学院,教育部环境污染过程与基准重点实验室,天津市城市生态环境修复与污染防治重点实验室,天津,300071
2. 南开大学环境科学与工程学院,教育部环境污染过程与基准重点实验室,天津市城市生态环境修复与污染防治重点实验室,天津,300071;中国科学院沈阳应用生态研究所,中国科学院陆地生态过程重点实验室,辽宁沈阳,110016
基金项目:国家自然科学基金资助项目
摘    要:以棕壤、褐土和红壤为研究对象,比较了不同浸提方法,不同浸提剂对土壤中土霉素的浸提效率.结果表明,在所用的3种方法中,采用振荡浸提方法,以及Na2EDTA-McIlvaine缓冲液对土霉素具有稳定、高效的浸提回收率.土霉素形态初步分析连续浸提步骤为:以H2O、0.1mol/L CaCl2、和Na2EDTA-McIlvaine缓冲液为浸提剂依次浸提可分别得到水溶态、可交换态、吸附态和固定态土霉素.3种土壤中土霉素形态呈现吸附态>可交换态>水溶态的规律.

关 键 词:土霉素  浸提方法  土壤  化学形态  
收稿时间:2010-10-03;

Compare of different oxytetracycline extraction methods in the three soils
YU Qiang,BAO Yan-yu,LI Yan-mei,ZHOU Qi-xing,LIU Yu-xia.Compare of different oxytetracycline extraction methods in the three soils[J].China Environmental Science,2011,31(6):951-957.
Authors:YU Qiang  BAO Yan-yu  LI Yan-mei  ZHOU Qi-xing  LIU Yu-xia
Institution:YU Qiang1,BAO Yan-yu1,LI Yan-mei1,ZHOU Qi-xing1,2,LIU Yu-xia1(1.Key Laboratory of Pollution Processes and Environmental Criteria,Ministry of Education,Tianjin Key Laboratory of Environmental Remediation and Pollution Control,College of Environmental Science and Engineering,Nankai University,Tianjin 300071,China,2.Key Laboratory of Terrestrial Ecological Process,Institute of Applied Ecology,Chinese Academy of Sciences,Shenyang 110016,China)
Abstract:Recoveries of oxytetracycline extracted were discussed with different extractants and extraction processes in the brown,cinnamon,and red soil.Stable and efficient extracted recovery could be achieved by using Na2EDTA-McIlvaine as a extractant in the shake flask extraction.In addition,a sequential extraction procedure was developed to study the chemical speciation of oxytetracycline in the soils.The soils were extracted by H2O,0.1mol/L CaCl2,and Na2EDTA-McIlvaine in order.As a result,water-soluble,exchangeab...
Keywords:oxytetracycline  extraction method  soil  chemical speciation  
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