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北京冬季大气中多溴联苯醚的污染水平和分布特征
引用本文:胡永彪,李英明,耿大玮,王璞,张捷,张庆华,江桂斌.北京冬季大气中多溴联苯醚的污染水平和分布特征[J].中国环境科学,2013,33(1):9-13.
作者姓名:胡永彪  李英明  耿大玮  王璞  张捷  张庆华  江桂斌
作者单位:华中农业大学资源与环境学院;中国科学院生态环境研究中心环境化学与生态毒理学国家重点实验室
基金项目:国家自然科学基金资助项目(20907059,21007085,21107121);中央高校基本科研业务费专项资金资助(2012ZYTS030)
摘    要:2010年11月至2011年2月利用聚氨酯泡沫(PUF)大气被动采样技术采集了北京市海淀、朝阳、丰台、石景山、昌平、大兴、通州等区域的大气样品,采用高分辨气相色谱/高分辨质谱联用法(HRGC/HRMS)分析了其中13种多溴联苯醚(PBDEs)同族体的污染浓度和分布特征.结果表明,北京大气中PBDEs总含量(Σ13PBDEs)为0.97~41.1pg/m3,平均值为7.85pg/m3.在区域分布规律方面呈现东南地区的采样点污染物浓度明显高于西北地区,工业地区和人口密集的商业地区明显高于郊区和背景对照区的分布特征.

关 键 词:多溴联苯醚  大气被动采样  北京大气  
收稿时间:2012-04-10;

Levels and distribution of polybrominated diphenyl ethers in the ambient air of Beijing during winter
HU Yong-biao,LI Ying-ming,GENG Da-wei,WANG Pu,ZHANG Jie,ZHANG Qing-hua,JIANG Gui-bin.Levels and distribution of polybrominated diphenyl ethers in the ambient air of Beijing during winter[J].China Environmental Science,2013,33(1):9-13.
Authors:HU Yong-biao  LI Ying-ming  GENG Da-wei  WANG Pu  ZHANG Jie  ZHANG Qing-hua  JIANG Gui-bin
Institution:1.College of Resources and Environment,Huazhong Agricultural University,Wuhan 430070,China;2.State Key Laboratory of Environmental Chemistry and Ecotoxicology,Research Center for Eco-Environmental Sciences,Chinese Academy of Sciences,Beijing 100085,China)
Abstract:Polyurethane foam (PUF) passive air sampling was conducted in Haidian, Chaoyang, Fengtai, Shijingshan, Changping, Daxing, and Tongzhou District of Beijing between November 2010 and February 2011. The air concentrations of 13 polybrominated diphenyl ether (PBDE) congeners were analyzed with high resolution gas chromatography/high resolution mass spectrometry (HRGC/HRMS). The air concentrations of PBDEs (Σ13PBDEs) ranged from 0.97 to 41.1 pg/m3 (average 7.85pg/m3). Investigation of the distribution characteristics showed that the concentrations of PBDEs in the southeast region were significantly higher than those in northwest region, and the PBDEs levels in industrial areas and business districts were higher than those in suburbs and background areas.
Keywords:PBDEs  passive air sampling  Beijing air
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