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蛭石氨氮吸附量与起始溶液浓度和介质用量的函数关系
引用本文:吴晓芙,胡日利,聂发辉,王 平,李科林.蛭石氨氮吸附量与起始溶液浓度和介质用量的函数关系[J].环境科学研究,2005,18(1):64-66.
作者姓名:吴晓芙  胡日利  聂发辉  王 平  李科林
作者单位:中南林学院,湖南,株洲,412006
基金项目:中挪政府间技术合作项目(国科外字[1996]339),湖南省教育厅2004年产业化研究项目
摘    要:测定了给定pH和温度条件下反应平衡时NH4Cl溶液中蛭石的氨氮吸附量。结果显示,平衡时蛭石的氨氮吸附量Qe与溶液起始的氨氮质量浓度C和单位体积溶液的介质用量W的函数关系可用Langmuir方程描述,其等温吸附通式为:Qe=qmCW/qm(Kw W) C]。式中,单位介质吸附容量qm和介质系数Kw是独立于C和W的常数;qm代表介质对溶质的吸附能力;Kw代表介质与氨氮的亲和力。

关 键 词:蛭石  氨氮  吸附等温曲线  浓度系数  介质系数  吸附容量
文章编号:1001-6929(2005)01-0064-03
收稿时间:2004/9/27 0:00:00

Sorption of NH4+-N by Vermiculite Minerals as a Function of Initial Solution Concentration and Sorbent Quantity
WU Xiao-fu,HU Yue-li,NIE Fa-hui,WANG Ping and LI Ke-lin.Sorption of NH4+-N by Vermiculite Minerals as a Function of Initial Solution Concentration and Sorbent Quantity[J].Research of Environmental Sciences,2005,18(1):64-66.
Authors:WU Xiao-fu  HU Yue-li  NIE Fa-hui  WANG Ping and LI Ke-lin
Institution:Central South Forestry University, Zhuzhou 412006, China;Central South Forestry University, Zhuzhou 412006, China;Central South Forestry University, Zhuzhou 412006, China;Central South Forestry University, Zhuzhou 412006, China;Central South Forestry University, Zhuzhou 412006, China
Abstract:Tests were conducted to measure the quantity of NH~+_4-N sorption at equilibrium by vermiculite minerals in NH_4Cl solution under constant pH and temperature conditions with objective to providing theoretical argument and as well basic parameters for use of vermiculite to remove NH~+_4-N in wastewater treatment. Analytical results showed that the relation of NH~+_4-N sorption quantity by vermiculite minerals at equilibrium Q_e with initial solution NH~+_4-N concentration C and sorbent quantity W can be described using Langmuir equation, with a common thermal sorption form: Q_e = q_mCW/q_m(K_W+W) +C]. The maximum sorption quantity per unit sorbent q_m and the medium coefficient K_W are constant terms independent of both C and W, of which q_m represents unit medium sorption capacity while K_W reflects the affinity of sorbent to NH~+_4-N.
Keywords:vermiculite  NH~+_4-N  thermal sorption curve  concentration coefficient  medium coefficient  sorption capacity
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