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活性炭对含铜制药废水的吸附特性
引用本文:刘风华,宋存义,宋永会,曾 萍,段 亮,肖书虎,邱光磊.活性炭对含铜制药废水的吸附特性[J].环境科学研究,2011,24(3):308-312.
作者姓名:刘风华  宋存义  宋永会  曾 萍  段 亮  肖书虎  邱光磊
作者单位:1.北京科技大学土木与环境工程学院, 北京 100083;中国环境科学研究院城市水环境研究室, 北京 100012
基金项目:国家水体污染控制与治理科技重大专项
摘    要:以粉末活性炭为吸附剂,采用批式试验,研究静态吸附对黄连素脱铜废水中Cu2+的去除效果,分析了吸附剂投加量(5~50 g/L),pH(1.0~5.0)和接触时间(20~600 min)对吸附效果的影响. 当pH为2.4,吸附剂投加量为30 g/L时,反应300 min即可达到吸附平衡状态. 通过对吸附动力学和吸附等温线的模型分析发现,二级吸附动力学模型能够更好地描述试验结果,对吸附平衡数据的拟合采用Langmuir吸附等温线优于采用Freundlich吸附等温线. 

关 键 词:吸附    活性炭    含铜废水    动力学    等温线
收稿时间:2010/8/21 0:00:00
修稿时间:2010/11/6 0:00:00

Adsorption Characteristics of Cu2+ from Pharmaceutical Wastewater onto Activated Carbon
LIU Feng-hu,SONG Cun-yi,SONG Yong-hui,ZENG Ping,DUAN Liang,XIAO Shu-hu and QIU Guang-lei.Adsorption Characteristics of Cu2+ from Pharmaceutical Wastewater onto Activated Carbon[J].Research of Environmental Sciences,2011,24(3):308-312.
Authors:LIU Feng-hu  SONG Cun-yi  SONG Yong-hui  ZENG Ping  DUAN Liang  XIAO Shu-hu and QIU Guang-lei
Institution:1.Civil and Environmental Engineering School, University of Science and Technology Beijing, Beijing 100083, China;Research Center of Urban Water Environment, Chinese Research Academy of Environmental Sciences, Beijing 100012, China2.Civil and Environmental Engineering School, University of Science and Technology Beijing, Beijing 100083, China3.Research Center of Urban Water Environment, Chinese Research Academy of Environmental Sciences, Beijing 100012, China
Abstract:The removal efficiency of Cu2 + static adsorption from berberin wastewater by powdered activated carbon was studied in a batch adsorption system.Factors affecting copper ion adsorption,such as pH(1.0-5.0),adsorbent dosage(5-50 g /L) and reaction time(20-600 min),were investigated.When the pH was 2.4 and the adsorbent dosage was 30 g /L,the equilibrium of the adsorption process was established in about 300 min.A comparison of kinetic models and isotherm models of adsorption showed that the adsorption system was better described by a second-order adsorption kinetic model.The adsorption equilibrium data fit better with the Langmuir isotherm than with the Freundlich isotherm.
Keywords:adsorption  activated carbon  wastewater containing copper  kinetics  isotherm
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