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不同粒径降尘中痕量金属元素Cu、Pb、Zn、Cr的形态分析
引用本文:高连存,冯素萍,何桂华,王淑仁,唐炳迎.不同粒径降尘中痕量金属元素Cu、Pb、Zn、Cr的形态分析[J].环境科学研究,1995,8(4):5-39.
作者姓名:高连存  冯素萍  何桂华  王淑仁  唐炳迎
作者单位:山东大学环境科学中心,山东工业大学化工系
摘    要:运用Tessler形态分类法和石墨炉原子吸收分光光度法研究了不同粒径降尘样品中痕量金属元素Cu、Pb、Zn、Cr的存在形态,讨论了不同存在形态的分布规律。结果表明,Cu、Pb、Zn、Cr在降尘中的主要形态按顺序分别为有机结合态、铁锰氧化物结合态、铁锰氧化物结合态、残渣晶格态,其活性顺序为Zn>Pb>Cu>Cr;4种元素的可交换态、碳酸盐结合态、铁锰氧化物结合态在小颗粒中的分布均比在大颗粒中占优势,说明小颗粒中金属元素较为活泼,其环境危害性更大。

关 键 词:形态分析,铜,铅,锌,铬,降尘

Specification of Cu, Pb,Zn,Cr in Dust of Different Diameters
GAO Ljancun,FENG Suping,HE Guihua,WANG Shuren.Specification of Cu, Pb,Zn,Cr in Dust of Different Diameters[J].Research of Environmental Sciences,1995,8(4):5-39.
Authors:GAO Ljancun  FENG Suping  HE Guihua  WANG Shuren
Abstract:Various Cu,Pb,Zn and Cr in dust of different diameters were studted using Tesslerscheme,and the distribution pattern was revealed.The results indicated that the dominant form ofCu,Pb,Zn and Cr was bound to organic matter, Fe-Mn oxides,Fe-Mn oxides and residual. Sotheir activity order was Zn > Pb > Cu > Cr,The exchangeable metals bound to carbonates and Fe-Mn oxides of four heavy metals in small particles were dominant compared with those in large particles. This demonstrates that heavy metals in small particles were more active and harmful.
Keywords:Specialty  Copper  Lead  Zinc  Chromium  Dust  
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