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Bio-F生物吸附剂对水中铁锰的去除与特性
引用本文:赵良元 ,朱迟,蒋金辉,杨娇艳,赵进,杨劭.Bio-F生物吸附剂对水中铁锰的去除与特性[J].环境科学研究,2012,25(4):425-430.
作者姓名:赵良元   朱迟  蒋金辉  杨娇艳  赵进  杨劭
作者单位:华中师范大学生命科学学院,湖北武汉430079
基金项目:国家水利部948项目(200731);中央高校科研基本业务费(CCNU09A01027);国家自然科学基金项目(30900054)
摘    要:以Bio-F(Bio-F生物吸附剂)为材料,研究其对水中Fe2+和Mn2+的去除能力与特性. 结果表明,Bio-F可同时去除水中Fe2+和Mn2+且吸附过程符合Lagergren一级动力学模型. Langmuir吸附等温线能较好地描述Bio-F吸附Fe2+和Mn2+的过程,表现为单分子层化学优惠吸附,其对Fe2+和Mn2+的最大饱和吸附量分别达491和380 mgg. Bio-F对Fe2+和Mn2+的吸附为吸热反应且在pH 6~7范围内可保持86%以上吸附能力(P>005). 较高的c(Ca2+)和c(Mg2+)可明显抑制Bio-F去除Fe2+和Mn2+的能力(P<005),但高c(PO43-)则可促进该吸附过程(P>005). Bio-F经10次再生后对Fe2+和Mn2+的去除率分别达9727%和9467%. Bio-F无毒安全,采用Bio-F处理高铁锰饮用水具有应用潜力. 

关 键 词:        Bio-F    吸附

Iron and Manganese Removal from Water by Bioadsorbent Bio-F
ZHAO Liang-yuan,ZHU Chi,JIANG Jin-hui,YANG Jiao-yan,ZHAO Jin and YANG Shao.Iron and Manganese Removal from Water by Bioadsorbent Bio-F[J].Research of Environmental Sciences,2012,25(4):425-430.
Authors:ZHAO Liang-yuan  ZHU Chi  JIANG Jin-hui  YANG Jiao-yan  ZHAO Jin and YANG Shao
Institution:College of Life Sciences,Central China Normal University, Wuhan 430079, China
Abstract:The adsorption capabilities and characteristics of Fe2+ and Mn2+ in water by a new bioadsorbent(Bio-F) were studied.It was found that Bio-F could effectively remove Fe2+ and Mn2+ simultaneously from water via adsorption,and the adsorption kinetics data fitted the Lagergren first-order equation.The adsorption process of Fe2+ and Mn2+ removal could be described by the Langmuir adsorption isotherm.The maximum adsorption capacities for Fe2+ and Mn2+ were 4.91 and 3.80 mgg respectively,and the adsorption process was an endothermic process.The removal rates of Fe2+ and Mn2+ were maintained above 86% at pH 6-7(P>0.05).The removal rates of Fe2+ and Mn2+ were significantly inhibited by Ca2+ and Mg2+ at high concentrations(P>0.05).In contrast,the removal rates were enhanced by PO43-(P>0.05).The removal rates reached 97.27% for Fe2+ and 94.67% for Mn2+ after ten regenerations.Since Bio-F is non-toxic,the results indicated that Bio-F could be potentially applied for Fe2+ and Mn2+ removal from drinking water in rural areas.
Keywords:iron  manganese  Bio-F  adsorption
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