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贵州碳酸盐岩风化壳中晶体石英的硅同位素组成及硅质来源探讨
引用本文:姜立君,王世杰,刘秀明,田世洪.贵州碳酸盐岩风化壳中晶体石英的硅同位素组成及硅质来源探讨[J].地球与环境,2009,37(1).
作者姓名:姜立君  王世杰  刘秀明  田世洪
作者单位:1. 中国科学院地球化学研究所环境地球化学国家重点实验室,贵阳,550002;中国科学院研究生院,北京,100039
2. 中国科学院地球化学研究所环境地球化学国家重点实验室,贵阳,550002
3. 中国地质科学院矿产资源研究所,北京,100037;国土资源部同位素地质开放重点实验室,北京,100037
基金项目:国家重点基础研究发展计划项目(2006CB403200);;国家自然科学基金(40371012)
摘    要:本文报道了黔北、黔东地区三个碳酸盐岩风化壳剖面中晶体石英的δ30Si值,利用硅同位素作为示踪剂,通过分析剖面中晶体石英的硅同位素组成来判别其硅质来源。结果表明:晶体石英的δ30Si值在0.8‰~1.7‰范围内,具有较高的同位素组成特征,与火山和热液(水)作用产物的δ30Si值不同,结合已有的资料证明晶体石英与火山或热液(水)作用无直接关系,而是来自碳酸盐岩酸不溶物中含硅物质风化产生的硅质流体,其中以硅酸矿物风化释放的硅质流体为主。利用植物岩中Ge/Si很小的特点来验证植物作用对研究剖面中硅质流体的影响,结果表明植物作用的贡献相对较小,但在表土层植物作用的影响可能不容忽视。

关 键 词:风化壳  晶体石英  硅同位素  硅质来源

Silicon Isotopic Composition and Silica Source of Quartz Crystals in the Weathering Crusts of Carbonate Rocks,Guizhou Province
JIANG Li-jun,WANG Shi-jie,LIU Xiu-ming,TIAN Shi-hong.Silicon Isotopic Composition and Silica Source of Quartz Crystals in the Weathering Crusts of Carbonate Rocks,Guizhou Province[J].Earth and Environment,2009,37(1).
Authors:JIANG Li-jun  WANG Shi-jie  LIU Xiu-ming  TIAN Shi-hong
Institution:1.The State Key Laboratory of Environmental Geochemistry;Institure of Geochemistry;Chinese Academy of Sciences;Guiyang 550002;China;2.Graduate School of the Chinese Academy of Sciences;Beijing 100039;3.Institute of Mineral Resources;Chinese Academy of Geological Sciences;Beijing 100037;4.Key Laboratory on Isotope Geology;Ministry of Land and Resources;China
Abstract:Reported in this paper are the δ30Si values of quartz crystals in three weathering crusts of carbonate rocks in northern and eastern Guizhou Province.The source of silica for the quartz crystals was estimated based on their δ30Si values.The δ30Si values of quartz crystals range from 0.8‰ to 1.7‰,differing from those of samples resultant from volcanism and hydrothormalism.It is suggested that the source of silica can not be directly related to volcanism and hydrothermalism.The silica may have been derived from the dissolution of "insoluble" constituents in the parent rocks,mainly from feldspars and other silicate minerals.Ge/Si ratios were used to study biogenic silicon in the profiles,which suggest that except that biogenic silicon in the top soil may have little contribution to the silica source of quartz crystals in the work profiles.
Keywords:weathering crust  quartz crystal  silicon isotope  the source of silica  
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