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常见金属硫化物电化学反应环境效应及其影响因素分析
引用本文:郑凯,王璐颖,金国恒,李和平,刘庆友.常见金属硫化物电化学反应环境效应及其影响因素分析[J].地球与环境,2015,43(6):714-720.
作者姓名:郑凯  王璐颖  金国恒  李和平  刘庆友
作者单位:1. 中国科学院地球化学研究所, 地球内部物质高温高压科学院重点实验室, 贵阳 550081;2. 中国科学院大学, 北京 100039
基金项目:国家高技术研究发展计划(2010AA09Z207);中国科学院地球化学研究所"135"项目;贵州省科技攻关项目(SY[2011]3088)。
摘    要:金属硫化物矿物作为重要的金属矿产资源之一,在自然界广泛分布并易氧化(电化学反应)引起重金属离子和酸性矿山废水污染的环境效应。本文以黄铁矿和黄铜矿为例全面分析了金属硫化物矿物环境效应产生机制,以及影响金属硫化物矿物电化学反应的各种因素,指出了当前研究存在的不足。这对金属硫化物矿区环境污染的源头控制与修复具有重要的指导意义。

关 键 词:金属硫化物  电化学反应  环境效应  影响因素
收稿时间:2015/3/24 0:00:00
修稿时间:2015/5/22 0:00:00

Environmental Effects of Electrochemical Interactions of Common Sulfide Minerals and Their Influence Factors
ZHENG Kai,WANG Luying,JIN Guoheng,LI Heping,LIUQingyou.Environmental Effects of Electrochemical Interactions of Common Sulfide Minerals and Their Influence Factors[J].Earth and Environment,2015,43(6):714-720.
Authors:ZHENG Kai  WANG Luying  JIN Guoheng  LI Heping  LIUQingyou
Institution:1. Key Laboratory of High-temperature and High-pressure Study of the Earth''s Interior, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, 550002, China;2. University ofChinese Academy of Sciences, Beijing, 100039, China
Abstract:Metal sulfide minerals is one of the most important metallic mineral resources, they are widely distributed in nature and can easily be oxidized (electrochemical reaction) resulting in environmental effects, such as pollution of heavy metal ions and acid mine drainage. In this article, pyrite and chalcopyrite were selected as examples to comprehensive analysis of the generation mechanisms of metal sulfide minerals environmental effects, analysis the various factors affecting the electrochemical reactions of the metal sulfide minerals,simultaneously, and point out the defects and disadvantages appeared in current researches. This has important guiding significance for source control and remediation of environmental contamination in metal sulfide mine areas.
Keywords:metalsulfide  electrochemical interaction  environmental effect  influence factor
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