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上海市饮用水中痕量土臭素和二甲基异冰片年变化规律及来源研究
引用本文:马晓雁,高乃云,李青松,刘成,顾国芬.上海市饮用水中痕量土臭素和二甲基异冰片年变化规律及来源研究[J].环境科学,2008,29(4):902-908.
作者姓名:马晓雁  高乃云  李青松  刘成  顾国芬
作者单位:1. 同济大学污染控制与资源化研究国家重点实验室,上海,200092
2. 上海市杨树浦水厂水质分析室,上海,200092
基金项目:国家高技术研究发展计划(863计划) , 国家科技攻关项目 , 国家重点实验室基金
摘    要:采用液液微萃取-气相色谱/质谱联用测定饮用水中痕量异嗅物质--土臭素(geosmin,GSM)和二甲基异冰片(2-Methylisoborneol,2-MIB或MIB).对上海市饮用水水源以及某水厂工艺出水进行调查发现,土霉昧的来源主要为2-MIB,异嗅问题暴发季节为7~10月,7、8月份达到顶峰,原水中2-MIB的最高检出浓度可达152.82 ng/L.水厂出水中最高检出浓度为97.94 ng/L.初步的来源分析推断2-MIB为水中颤藻的代谢产物.

关 键 词:异嗅物质  土臭素  二甲基异冰片  气相色谱-质谱  饮用水
文章编号:0250-3301(2008)04-0902-07
收稿时间:2007/4/24 0:00:00
修稿时间:2007年4月24日

Source and Fluctuation of Trace Geosmin and 2-MIB in Drinking Water of Shanghai
MA Xiao-yan,GAO Nai-yun,LI Qing-song,LIU Cheng and GU Guo-fen.Source and Fluctuation of Trace Geosmin and 2-MIB in Drinking Water of Shanghai[J].Chinese Journal of Environmental Science,2008,29(4):902-908.
Authors:MA Xiao-yan  GAO Nai-yun  LI Qing-song  LIU Cheng and GU Guo-fen
Institution:State Key Laboratory of Pollution Control and Resource Reuse, College of Environmental Science and Engineering, Tongji University, Shanghai 200092, China. mayaner620@163.com
Abstract:Liquid-liquid microextraction/GC/MS analysis method was employed in detecting trace odorants in drinking water. A-year-long investigation on odor chemicals was carried out in source water and drinking water in a certain waterworks of Shanghai. The results showed that 2-MIB was the main contaminant which induce disgusting odor to drinking water of Shanghai in July, August, September and October in a year with the peak concentration of 2-MIB 152.82 ng/L in raw water and 97.94 ng/L in finished water from waterworks. Oscillatoria was suspected as the resource of 2-MIB.
Keywords:odorants  geosmin  2-methylisoborneol  GC-MS  drinking water
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