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高压电晕与臭氧联用降解对硝基苯酚
引用本文:潘理黎,严国奇,郑飞燕,梁国伟,浮建军.高压电晕与臭氧联用降解对硝基苯酚[J].环境科学,2005,26(6):115-118.
作者姓名:潘理黎  严国奇  郑飞燕  梁国伟  浮建军
作者单位:浙江工业大学生物与环境工程学院,杭州,310032;中国计量学院,杭州,310018
基金项目:浙江省自然科学基金项目(202080)
摘    要:利用臭氧的强氧化性和电晕的高能量降解有毒有害大分子为较低毒性的小分子,以提高可生化性.在pH8~9的条件下,高压电晕与臭氧联用处理对硝基苯酚模拟废水30min,对硝基苯酚的降解率为96.8%,TOC的降解率为38.6%.设计了先电晕后臭氧、先臭氧后电晕分别处理和电晕与臭氧联用处理3种实验方案,结果表明:电晕与臭氧联用处理效率要高于分别处理效率,电晕与臭氧联用具有协同作用;对降解含苯环的大分子效率高,对降解直链分子的效率相对较低.

关 键 词:高压电晕  臭氧  协同效应  对硝基苯酚
文章编号:0250-3301(2005)06-0115-04
收稿时间:2004-11-02
修稿时间:2004-11-022004-12-28

Degradation of p-nitrophenol by High Voltage Pulsed Discharge and Ozone Processes
PAN Li-li,YAN Guo-qi,ZHENG Fei-yan,LIANG Guo-wei and FU Jian-jun.Degradation of p-nitrophenol by High Voltage Pulsed Discharge and Ozone Processes[J].Chinese Journal of Environmental Science,2005,26(6):115-118.
Authors:PAN Li-li  YAN Guo-qi  ZHENG Fei-yan  LIANG Guo-wei and FU Jian-jun
Institution:1. Zhejiang University of Technology, College of Biology and Environment Engineering, Hangzhou 310032, China; 2. China Institute of Metrology, Hangzhou 310018, China
Abstract:The vigorous oxidation by ozone and the high energy by pulsed discharge are utilized to degrade the big hazardous molecules. And these big hazardous molecules become small and less hazardous by this process in order to improve the biodegradability. When pH value is 8- 9, the concentration of p-nitrophenol solution can be degraded by 96.8% and the degradation efficiency of TOC is 38.6 % by ozone and pulsed discharge treatment for 30mins. The comparison results show that the combination treatment efficiency is higher than the separate, so the combination of ozone and pulsed discharge has high synergism. It is approved that the phenyl degradation efficiency is high and the degradation efficiency of linear molecules is relative low.
Keywords:high voltage pulsed discharge  ozone  synergism  p-nitrophenol
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