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微生物燃料电池改性阳极处理PTA废水
引用本文:孙靖云,范梦婕,陈英文,祝社民,沈树宝.微生物燃料电池改性阳极处理PTA废水[J].环境科学,2017,38(7):2893-2900.
作者姓名:孙靖云  范梦婕  陈英文  祝社民  沈树宝
作者单位:南京工业大学生物与制药工程学院, 南京 210009,南京工业大学生物与制药工程学院, 南京 210009,南京工业大学生物与制药工程学院, 南京 210009;南京信息工程大学环境科学与工程学院, 江苏省环境净化材料工程技术研究中心, 南京 210044,南京工业大学材料科学与工程学院, 南京 210009,南京工业大学生物与制药工程学院, 南京 210009
基金项目:国家自然科学基金项目(21106072,51608261);江苏省环境净化材料工程技术研究中心(ECM)开放课题项目(KFK1503);江苏高校优势学科建设工程项目(PAPD);江苏省科技厅项目(BE2016769);江苏省普通高校研究生科研创新计划项目(SJZZ16-0138)
摘    要:探讨了不同改性阳极对微生物燃料电池(microbial fuel cell,MFC)产电性能及其对MFC处理难降解废水能力的影响.以单室空气阴极为基础,利用0.1 g电气石、质量分数75%二氧化锰/埃洛石纳米管(manganese bioxide/halloysite nanotube,MnO_2/HNT)和多壁碳纳米管-羧基(multi-walled carbon nanotube-carboxyl,MWCNT-COOH)对MFC阳极进行修饰.结果表明,不同改性阳极的MFC对含精对苯二甲酸(purified terephthalic acid,PTA)废水的去除率均高于70%,且化学需氧量(chemical oxygen demand,COD)去除率在79%以上.相较于其他几种改性阳极,以MWCNT-COOH改性材料作阳极的MFC产生的最大输出电压最高,获得的最大功率密度最高,分别为529 mV和252.73 mW·m~(-2).

关 键 词:微生物燃料电池  阳极修饰  电气石  二氧化锰/埃洛石纳米管(MnO2/HNT)  MWCNT-COOH  PTA废水
收稿时间:2016/11/24 0:00:00
修稿时间:2017/2/17 0:00:00

Treatment of PTA Wastewater by Modified Anode Microbial Fuel Cell
SUN Jing-yun,FAN Meng-jie,CHEN Ying-wen,ZHU She-min and SHEN Shu-bao.Treatment of PTA Wastewater by Modified Anode Microbial Fuel Cell[J].Chinese Journal of Environmental Science,2017,38(7):2893-2900.
Authors:SUN Jing-yun  FAN Meng-jie  CHEN Ying-wen  ZHU She-min and SHEN Shu-bao
Institution:College of Biological and Pharmaceutical Engineering, Nanjing Tech University, Nanjing 210009, China,College of Biological and Pharmaceutical Engineering, Nanjing Tech University, Nanjing 210009, China,College of Biological and Pharmaceutical Engineering, Nanjing Tech University, Nanjing 210009, China;Jiangsu Engineering Technology Research Center of Environmental Cleaning Material, School of Environmental Science and Engineering, Nanjing University of Information Science and Technology, Nanjing 210044, China,College of Materials Science and Engineering, Nanjing Tech University, Nanjing 210009, China and College of Biological and Pharmaceutical Engineering, Nanjing Tech University, Nanjing 210009, China
Abstract:The purpose of this study was to investigate the effect of different modified anodes on the microbial fuel cell(MFC) and the effect of MFC on the treatment of refractory wastewater. Based on a single room air cathode, the anode of MFC was modified by 0.10 g of tourmaline, 75% manganese bioxide/halloysite nanotube(MnO2/HNT) and multi-walled carbon nanotube-carboxyl(MWCNT-COOH), respectively. The results showed that, the removal rate of purified terephthalic acid(PTA) was higher than 70%, and the chemical oxygen demand(COD) removal rate was more than 79% in MFC with different modified anodes. Compared with others, MFC with MWCNT-COOH modified anode obtained the maximum output voltage and maximum power density, which were 529 mV and 252.73 mW·m-2, respectively.
Keywords:microbial fuel cell(MFC)  anode modification  tourmaline  manganese bioxide/halloysite nanotube(MnO2/HNT)  MWCNT-COOH  PTA wastewater
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