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灭幼脲(Ⅲ)在模拟大气条件下光解动力学的初步研究
引用本文:刘国光,金祖亮,徐晓白.灭幼脲(Ⅲ)在模拟大气条件下光解动力学的初步研究[J].环境科学,1990(5):12-16.
作者姓名:刘国光  金祖亮  徐晓白
作者单位:中国科学院生态环境研究中心 (刘国光,金祖亮),中国科学院生态环境研究中心(徐晓白)
摘    要:本文初步研究灭幼脲(Ⅲ)在模拟大气条件下的光化学行为,测定定在不同气体气流环境中灭幼脲(Ⅲ)的反应速率。结果表明,灭幼脲(Ⅲ)在氮气及空气中的光解反应表现为动力学一级形式,而在氧气中则近似为二级反应。

关 键 词:灭幼脲(Ⅲ)  光解动力学  模拟大气
收稿时间:1990/3/23 0:00:00

Preliminary Study of the Kinetics of Photodecomposition of Benzamide, 2-chlora-N(((4 chlorophenyl)amino)carbonyl)under Simulated Atmospheric Conditions
Liu Guoguang,Jin Zuliang and Xu xiaobai.Preliminary Study of the Kinetics of Photodecomposition of Benzamide, 2-chlora-N(((4 chlorophenyl)amino)carbonyl)under Simulated Atmospheric Conditions[J].Chinese Journal of Environmental Science,1990(5):12-16.
Authors:Liu Guoguang  Jin Zuliang and Xu xiaobai
Institution:Research Center for Eco-Environmental Sciences, Academia Sinica, Beijing;Research Center for Eco-Environmental Sciences, Academia Sinica, Beijing;Research Center for Eco-Environmental Sciences, Academia Sinica, Beijing
Abstract:The kinetics of photodecomposition of benzamide, 2-chloro-N(((4-chorophenyl)amino)carbony) under simulated atmospheric conditions has been preliminarily studied in theis paper. The rate constants and half-lives of this compound in nitrogen, oxygen and air have been determined. The statistical treatment of experimental results indicates that the photoreaction in nitrogen and air is of the first order, while in oxygen is closer to that of the second order.
Keywords:kinetics of photoreaction  benzamide    
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