| 膜生物反应器处理甲苯性能及机制 |
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| 引用本文： | 叶杞宏,魏在山,肖盼,李华琴,张再利,樊青娟.膜生物反应器处理甲苯性能及机制[J].环境科学,2012,33(8):2558-2562. |
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| 作者姓名： | 叶杞宏 魏在山 肖盼 李华琴 张再利 樊青娟 |
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| 作者单位： | 中山大学环境科学与工程学院, 广东省环境污染控制与修复技术重点实验室, 广州 510275;中山大学环境科学与工程学院, 广东省环境污染控制与修复技术重点实验室, 广州 510275;中山大学环境科学与工程学院, 广东省环境污染控制与修复技术重点实验室, 广州 510275;中山大学环境科学与工程学院, 广东省环境污染控制与修复技术重点实验室, 广州 510275;中山大学环境科学与工程学院, 广东省环境污染控制与修复技术重点实验室, 广州 510275;中山大学环境科学与工程学院, 广东省环境污染控制与修复技术重点实验室, 广州 510275 |
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| 基金项目： | 广东省科技计划项目(2011A030700010);企业委托横向项目(7102651,7101614) |
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| 摘 要： | 采用膜生物反应器处理甲苯有机废气,研究了进气浓度、停留时间、循环液喷淋密度和pH值对甲苯去除率的影响.膜生物反应器能高效净化挥发性有机废气,甲苯去除率可达99%.适宜运行条件为:pH值为7.2、停留时间为6.4 s、循环液喷淋密度为2.5 m3.(m2.h)-1.采用GC-MS分析出口气样,研究结果表明乙醛酸(C2H2O3)和乙烯基甲酸(C3H4O2)为甲苯生物降解的中间产物.膜生物反应器处理甲苯机制为甲苯气体通过中空纤维膜传质到生物膜,被生物降解为乙醛酸和乙烯基甲酸,然后继续好氧降解为最终产物二氧化碳和水.
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| 关 键 词： | 膜生物反应器 挥发性有机物(VOCs) 甲苯 |
| 收稿时间： | 2011/10/4 0:00:00 |
| 修稿时间： | 2012/2/12 0:00:00 |
Mechanism and Performance of a Membrane Bioreactor for Treatment of Toluene Vapors |
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| YE Qi-hong,WEI Zai-shan,XIAO Pan,LI Hua-qin,ZHANG Zai-li and FAN Qin-juan.Mechanism and Performance of a Membrane Bioreactor for Treatment of Toluene Vapors[J].Chinese Journal of Environmental Science,2012,33(8):2558-2562. |
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| Authors: | YE Qi-hong WEI Zai-shan XIAO Pan LI Hua-qin ZHANG Zai-li and FAN Qin-juan |
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| Institution: | Guangdong Provincial Key Laboratory of Environmental Pollution Control and Remediation Technology, School of Environmental Science and Engineering, Sun Yat-sen University, Guangzhou 510275, China;Guangdong Provincial Key Laboratory of Environmental Pollution Control and Remediation Technology, School of Environmental Science and Engineering, Sun Yat-sen University, Guangzhou 510275, China;Guangdong Provincial Key Laboratory of Environmental Pollution Control and Remediation Technology, School of Environmental Science and Engineering, Sun Yat-sen University, Guangzhou 510275, China;Guangdong Provincial Key Laboratory of Environmental Pollution Control and Remediation Technology, School of Environmental Science and Engineering, Sun Yat-sen University, Guangzhou 510275, China;Guangdong Provincial Key Laboratory of Environmental Pollution Control and Remediation Technology, School of Environmental Science and Engineering, Sun Yat-sen University, Guangzhou 510275, China;Guangdong Provincial Key Laboratory of Environmental Pollution Control and Remediation Technology, School of Environmental Science and Engineering, Sun Yat-sen University, Guangzhou 510275, China |
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| Abstract: | The performance of a membrane bioreactor for treatment of toluene as a model pollutant is presented. Effects of toluene inlet concentration, residence time, spray density and pH of liquid phase on the toluene removal rate were evaluated. The experimental results showed that the toluene removal efficiency reached 99%. The optimal pH, residence time and spray density were 7.2, 6.4 s and 2.5 m3 ·(m2 ·h)-1, respectively. The gas-phase biodegradation intermediate products were acetaldehyde acid (C2H2O3) and vinyl formic acid (C3H4O2), which were identified by means of gas chromatography/mass spectrometry (GC/MS). The mechanism of toluene degradation using a membrane bioreactor can be described as the combination of mass transfer from hollow fiber membrane to biofilm and biological degradation. Toluene (C6H5CH3) and oxygen diffused from the gas phase to the wet layer of the biofilm and were then consumed by the microbial communities. Toluene was oxidized to the intermediate organic products such as acetaldehyde acid (C2H2O3) and vinyl formic acid (C3H4O2), and the intermediate products were then converted to CO2 and H2O through continuous biological oxidation reactions. |
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| Keywords: | membrane bioreactor volatile organic compounds (VOCs) toluene |
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