北京市大气环境中硫酸盐、硝酸盐粒径分布及存在形式

为了解北京市大气颗粒物中,二次硫酸盐、硝酸盐的存在形式及其含量,于2008年5月～2009年4月,利用MOUDI对北京市大气颗粒物分10级进行采样,利用离子色谱技术对各粒径范围大气颗粒物中的无机水溶性组分进行分析,并利用偏相关分析的方法确定其存在形式和估算其含量.结果表明,北京市大气颗粒物中水溶性硫酸盐和硝酸盐表现为单...

Mass Size Distributions and Existing Forms of Sulfate and Nitrate at Atmospheric Environment in Beijing

In order to understand the formations and the concentrations of the secondary sulfate and nitrate of PM10 in Beijing. From May 2008 to April 2009, MOUDI has been used to collect the PM10 samples in Beijing atmospheric environment and the ion chromatography has been used to analyze the inorganic water-soluble components of the PM10 samples. The results showed that the mass size distributions of soluble sulfate and nitrate of PM10 in Beijing were single-mode distribution and the peak rang was from 0.32 microm to 0.56 microm, and the primary formation ways was the chemical reaction in the gas phase. The results of partial correlation analysis indicated that the primary formations of sulfate and nitrate of PM10 in Beijing was (NH4)2SO4, NH4NO3, NaNO3, KNO3 and Ca(NO3)2. The mass concentration of secondary (NH4)2SO4 and NH4NO3 were (17.0 +/- 8.2) microg/m3 and (8.8 +/- 3.3) microg/m3 respectively, which accounted for (14.7 +/- 3.6)% and (7.6 +/- 2.2)% of PM10 respectively. The sum of them accounted for (22.3 +/- 4.3)% of PM10.