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油制气废水中毒害有机物分析及一般特征
引用本文:慎义勇,傅家谟,盛国英,韦朝海.油制气废水中毒害有机物分析及一般特征[J].环境科学,2001,22(1):109-113.
作者姓名:慎义勇  傅家谟  盛国英  韦朝海
作者单位:1. 中国科学院广州地球化学研究所有机地球化学国家重点实验室,广州,510640
2. 华南理工大学化工学院,广州,510641
基金项目:国家自然科学重点基金项目 (49632060);广东省自然科学基金项目(963043)
摘    要:对油制气废水特征进行较全面的调查和分析,给出GC/MS(气相色谱-质谱联用)分析的一般前处理流程、废水的一般特征数据及废水中芳烃类毒害有机物的GC/MS分析结果.废水中CODCr、BOD5、酚、氨氮、可萃取有机物的值分别可达(mg·L-1):400~600、60~80、20~30、60~80、170~200.GC-MS检测到79种芳烃类有机物,这些有机物进、出水浓度总和分别为140.79mg·L-1、129.11mg·L-1.分析数据表明油制气废水毒性强、较难进行生物处理.

关 键 词:油制气过程废水  毒害有机物  GC/MS分析
文章编号:0250-3301(2001)01-05-109
收稿时间:5/3/2000 12:00:00 AM
修稿时间:2000年5月3日

Analysis of Toxic Organic Compounds in MGP-Wastewater and Investigation of Wastewater's General Characteristics
Shen Yiyong,Fu Jiamo,Sheng Guoying and Wei Chaohai.Analysis of Toxic Organic Compounds in MGP-Wastewater and Investigation of Wastewater's General Characteristics[J].Chinese Journal of Environmental Science,2001,22(1):109-113.
Authors:Shen Yiyong  Fu Jiamo  Sheng Guoying and Wei Chaohai
Institution:SKLOG, Guangzhou Institute of Geochemistry, Chine Acaderny of Sciences, Guangzhou 510640, China. shenyy@gig.ac.cn
Abstract:A full-scale investigation and analysis of MGP(Manufacture Gas from Petroleum)-Wastewater was carried out in this study. It's the first time that this paper publicizes the wastewater's general data, pretreatment method of GC/MS analysis and compositions of toxic organic compounds. The concentrtion of wastewater's CODCg, BOD5, phenolic, N-NH4+ and extractive-organic is: 400 mg.L(-1)-600 mg.L-1, 60 mg.L(-1)-80 mg.L-1, 20 mg.L(-1)-30 mg.L-1, 60 mg.L(-1)-80 mg.L-1 and 170 mg.L(-1)-200 mg.L-1 respectively. There are 79 kinds of aromatic compounds were detected by GC/MS, the total concentration of influent and effluent is 140.79 mg.L-1 and 129.11 mg.L-1 respectively. The data approved that MGP-wastewater is toxic and difficult for bio-treatment.
Keywords:MGP-wastewater  toxic organic compounds  GC/MS analyis
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