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有机膨润土在Pb2+p-硝基苯酚复合污染中的吸附及机理
引用本文:沈学优,卢瑛莹,吴双双,孙俊杰,朱利中.有机膨润土在Pb2+p-硝基苯酚复合污染中的吸附及机理[J].环境科学,2004,25(3):168-170.
作者姓名:沈学优  卢瑛莹  吴双双  孙俊杰  朱利中
作者单位:1. 浙江大学环境科学系,杭州,310028
2. 浙江省环境保护科学设计研究院,杭州,310007
基金项目:国家自然科学基金资助项目(29777005;20277032);浙江省自然科学基金资助项目(GJ0202)
摘    要:以Pb2+p-硝基苯酚为代表污染物,用实验室模拟法研究了有机膨润土在重金属-有机物混合污染体系中的吸附行为.结果表明,在有机膨润土/Pb2+/p-硝基苯酚体系中,溶液中共存Pb2+会延缓p-硝基苯酚在有机膨润土上的吸附速率;Pb2+p-硝基苯酚产生竞争吸附,竞争作用的大小与溶液中p-硝基苯酚和Pb2+的浓度比c(酚/Pb)以及有机膨润土对污染物的吸附机制有关,相对于吸附机制以分配作用为主的100CTMAB-膨润土,Pb2+p-硝基苯酚在以表面吸附为主的100TMAB-膨润土上的竞争吸附更强.

关 键 词:有机膨润土  Pb2+  p-硝基苯酚  吸附
文章编号:0250-3301(2004)03-0168-03
收稿时间:2003/5/13 0:00:00
修稿时间:2003/8/17 0:00:00

Adsorption Behavior and Mechanisms in Dual-solutes of Pb2+ and p-Nitrophenol by Organobentonites
SHEN Xue-you,LU Ying-ying,WU Shuang-shuang,SUN Jun-jie and ZHU Li-zhong.Adsorption Behavior and Mechanisms in Dual-solutes of Pb2+ and p-Nitrophenol by Organobentonites[J].Chinese Journal of Environmental Science,2004,25(3):168-170.
Authors:SHEN Xue-you  LU Ying-ying  WU Shuang-shuang  SUN Jun-jie and ZHU Li-zhong
Institution:Department of Environmental Science, Zhejiang University, Hangzhou 310028, China.
Abstract:The sorption behavior for organobentonites to sorb organic pollutants from metal-organic pollutant systems were investigated.The results suggested that in organobentonite/Pb2+/p-nitrophenol solute systems,Pb2+ can slow the sorption velocity of organobentonite to adsorb p-nitrophenol from water.Pb2+ and p-nitriphenol exhibit a competitive effect.The competitive effects were relevant to ration of p-nitrophenol and Pb2+ and adsorption mechanisms of organobentonites.Bentonite modified with TMAB adsorbing contaminants primarily by a adsorption process,and the process exhibits a stonger competitive effect in multi-solute systemms.
Keywords:organobentonites  Pb2+  p-nitrophenol  adsorption
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