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硫铁比对再生水深度脱氮除磷的影响
引用本文:周彦卿,郝瑞霞,王珍,朱晓霞,万京京.硫铁比对再生水深度脱氮除磷的影响[J].环境科学,2016,37(6):2229-2234.
作者姓名:周彦卿  郝瑞霞  王珍  朱晓霞  万京京
作者单位:北京工业大学建筑工程学院, 北京市水质科学与水环境恢复工程重点实验室, 北京 100124,北京工业大学建筑工程学院, 北京市水质科学与水环境恢复工程重点实验室, 北京 100124,陕西省环境工程评估中心, 西安 710054,北京工业大学建筑工程学院, 北京市水质科学与水环境恢复工程重点实验室, 北京 100124,北京工业大学建筑工程学院, 北京市水质科学与水环境恢复工程重点实验室, 北京 100124
基金项目:国家自然科学基金项目(51378028)
摘    要:为了考察硫铁比对反硝化脱氮同步除磷效果的影响,进行了不同硫铁比的反硝化脱氮除磷静态实验,并对复合填料系统反硝化脱氮同步除磷作用进行了分析.结果表明,硫铁复合填料的脱氮除磷效果均显著高于单一填料;硫铁比是影响复合填料反硝化脱氮除磷效果的一个关键因素,当硫铁比(体积比)大于等于1∶1时,TN、TP去除率分别达到了85%和97%以上.复合填料脱氮除磷过程均满足二级动力学方程,系统脱氮作用主要依赖于异养反硝化和硫自养反硝化过程,而除磷主要由于海绵铁腐蚀产生的化学除磷作用.

关 键 词:再生水  复合填料  同步脱氮除磷  硫自养反硝化  化学除磷
收稿时间:2015/12/9 0:00:00
修稿时间:2016/1/12 0:00:00

Effects of Sulfur/sponge Iron Ratio for Deep Denitrification and Phosphorus Removal of Reclaimed Water
ZHOU Yan-qing,HAO Rui-xi,WANG Zhen,ZHU Xiao-xia and WAN Jing-jing.Effects of Sulfur/sponge Iron Ratio for Deep Denitrification and Phosphorus Removal of Reclaimed Water[J].Chinese Journal of Environmental Science,2016,37(6):2229-2234.
Authors:ZHOU Yan-qing  HAO Rui-xi  WANG Zhen  ZHU Xiao-xia and WAN Jing-jing
Institution:Key Laboratory of Beijing for Water Quality Science and Water Environmental Recovery Engineering, College of Architectural Engineering, Beijing University of Technology, Beijing 100124, China,Key Laboratory of Beijing for Water Quality Science and Water Environmental Recovery Engineering, College of Architectural Engineering, Beijing University of Technology, Beijing 100124, China,Envionmental Engineering Assessment Center of Shaanxi Province, Xi''an 710054, China,Key Laboratory of Beijing for Water Quality Science and Water Environmental Recovery Engineering, College of Architectural Engineering, Beijing University of Technology, Beijing 100124, China and Key Laboratory of Beijing for Water Quality Science and Water Environmental Recovery Engineering, College of Architectural Engineering, Beijing University of Technology, Beijing 100124, China
Abstract:To study the effects of sulfur/sponge iron ratio on denitrification and phosphorus removal, a series of static experiments were conducted using different ratios of sulfur and sponge iron. The results showed that the denitrification and phosphorus removal effect of sulfur/sponge iron composite fillers was significantly higher than that of single filler, and sulfur/sponge iron ratio was one of the key factors influencing nitrogen and phosphorus removal by composite fillers. When the volume ratio was equal to or greater than 1:1, the removal efficiency of TN and TP reached 85% and 97%, respectively. The denitrification and phosphorus removal process of the composite fillers both fitted second-order kinetic equation, the denitrification was dependent on heterotrophic denitrification and sulfur autotrophic denitrification; the phosphorus removal was mainly chemical phosphorus removal caused by sponge iron corrosion.
Keywords:reclaimed water  composite fillers  simultaneous nitrogen and phosphorus removal  sulfur autotrophic denitrification  chemical phosphorus removal
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